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Fig. B.1

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a) The H3O+ rotation diagram (triangles), calculated in the optically thin limit. The colored squares (red: ortho, blue: para) show the expected column density distribution for a formation temperature of Tform = 1000 K, and neglecting collisional relaxation. The two solid lines correspond to rotational temperatures of Trot = 250 and 600 K. b) The rotational temperature of the metastable level of H3O+ relative to the one as a function of the electron abundance χ(e) for two adopted values of Tgas (50 and 200 K) and four assumed values of (curves 1), 1 × 10-10 (2), 3 × 10-10 (3), and 1 × 10-9 cm3 s-1 (4).

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