Table 5
Spectroscopic parameters for the H-out-of-plane configurations.
| Parameter | Value | Parameter | Value | |||
|
|
||||||
| θ2 | 6.655 648(2600) | HKKK × 109 | 1195.553(5096) | |||
| φ 2 | 81.578 313(5700) | HKKJ × 109 | −461.461(1289) | |||
| HKJJ × 109 | −34. 508(420) | |||||
| h 2 | −5.394 756(8600) | HJJJ × 109 | −1.833(54) | |||
| h2k × 106 | 2914.209(47967) | hKK × 109 | 357.691(5396) | |||
| h2j × 106 | −1184.396(10193) | hKJ × 109 | 101.726(510) | |||
| f2 × 106 | −213.732(4497) | hJJ × 109 | −0.878(5) | |||
| A | 18 482.353 793(330) | LKKKK × 1012 | − 114.585(14390) | |||
| B | 6261.052 643(100) | LKKKJ × 1012 | 159.564(21585) | |||
| C | 4884.201 398(110) | LKKJJ × 1012 | −55.071(7495) | |||
| LKJJJ × 1012 | −5.095(48) | |||||
| ΔKK × 103 | 57.573 479(2000) | LJJJJ × 1012 | −0.058(8) | |||
| ΔKJ × 103 | −13.498 154(360) | lKKK × 1012 | −308.607(59958) | |||
| ΔJJ × 103 | 5.036 334(120) | |||||
| δK × 103 | 1.622 568(630) | |||||
| δJ × 103 | 1.540 159(21) | |||||
Notes. Parameters are in MHz except for θ2 and φ2, which are in degrees. Numbers in parentheses are one standard deviation in the same units as the last digit. Parameters are defined in Eqs. (12), (13), and (22) of Margulès et al. (2009) or are involved in the pure rotational Hamiltonian in the first of Eqs. (10) of the same reference.
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