Free Access
Upper level | Lower level |
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BF | A | log (gf) | Unc. | ||
Design. | (Å) | (cm-1) | Calc. | Exp. | Exp/Calc | (s-1) | (% in gf) | ||
4d3(4F)5p
3F
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4d4 5D3 | 2514.3531 | 39 759.692 | 0.012 | 0.013 | 1.089 | 2.06(6) | -1.76 | 13 |
4d4 5D4 | 2541.4244 | 39 336.195 | 0.067 | 0.069 | 1.033 | 1.09(7) | -1.02 | 12 | |
40561.02 cm-1 | 4d3(4F)5s 5F4 | 2700.5523 | 37 018.457 | 0.026 | 0.035 | 1.336 | 5.47(6) | -1.27 | 12 |
4d3(4F)5s 5F5 | 2745.3118 | 36 414.981 | 0.079 | 0.086 | 1.087 | 1.35(7) | -0.86 | 12 | |
4d4 3F4 | 3100.7738 | 32 240.645 | 0.025 | 0.025 | 0.984 | 3.88(6) | -1.30 | 17 | |
4d4 3G5 | 3372.5601 | 29 642.544 | 0.055 | 0.065 | 1.197 | 1.02(7) | -0.80 | 8 | |
4d3(4P)5s 5P3 | 3421.1646 | 29 221.428 | 0.015 | 0.018 | 1.158 | 2.77(6) | -1.36 | 12 | |
4d3(4F)5s 3F4 | 3717.0600 | 26 895.332 | 0.348 | 0.368 | 1.055 | 5.75(7) | 0.03 | 8 | |
4d3(4F)5s 3F3 | 3720.4532 | 26 870.790 | 0.080 | 0.105 | 1.304 | 1.64(7) | -0.51 | 8 | |
4d4 1G4 | 3879.3421 | 25 770.263 | 0.171 | 0.089 | 0.523 | 1.40(7) | -0.55 | 6 | |
4d3(2G)5s 3G4 | 4061.9711 | 24 611.648 | 0.021 | 0.027 | 1.274 | 4.27(6) | -1.02 | 9 | |
Residual | 0.099 | ||||||||
4d3(4P)5p
3P
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4d4 3F3 | 2956.8884 | 33 809.499 | 0.061 | 0.065 | 1.073 | 7.89(6) | -1.29 | 21 |
4d3(4P)5s 5P2 | 3237.9954 | 30 874.306 | 0.248 | 0.199 | 0.802 | 2.42(7) | -0.72 | 11 | |
41710.14 cm-1 | 4d4 1D2 | 3394.9714 | 29 446.922 | 0.151 | 0.153 | 1.008 | 1.85(7) | -0.80 | 11 |
4d3(4F)5s 3F2 | 3541.2454 | 28 230.683 | 0.099 | 0.124 | 1.244 | 1.50(7) | -0.85 | 11 | |
4d3(2P)5s 3P1 | 3691.1738 | 27 083.944 | 0.071 | 0.073 | 1.040 | 5.60(6) | -1.24 | 14 | |
4d3(2P)5s 3P2 | 3695.8960 | 27 049.388 | 0.183 | 0.193 | 1.057 | 2.35(7) | -0.62 | 11 | |
4d3(2D2)5s 3D1 | 4367.3789 | 22 890.623 | 0.035 | 0.037 | 1.041 | 4.48(6) | -1.19 | 16 | |
4d3(4P)5s 3P1 | 4699.5812 | 21 272.640 | 0.041 | 0.046 | 1.110 | 5.53(6) | -1.04 | 19 | |
Residual | 0.110 | ||||||||
4d3(4P)5p
3P
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4d4 5D0 | 2372.7316 | 42 132.646 | 0.024 | 0.014 | 0.598 | 1.93(6) | -2.31 | 22 |
4d4 5D1 | 2381.7200 | 41 973.662 | 0.026 | 0.018 | 0.690 | 2.37(6) | -2.22 | 18 | |
42132.65 cm-1 | 4d4 3P2 | 2866.8425 | 34 871.322 | 0.038 | 0.015 | 0.403 | 2.03(6) | -2.13 | 52 |
4d4 3F2 | 2887.0836 | 34 626.881 | 0.042 | 0.060 | 1.426 | 8.00(6) | -1.52 | 21 | |
4d3(4P)5s 5P1 | 3175.7747 | 31 479.219 | 0.263 | 0.273 | 1.038 | 3.64(7) | -0.78 | 11 | |
4d3(4P)5s 5P2 | 3194.2782 | 31 296.809 | 0.259 | 0.281 | 1.083 | 3.75(7) | -0.77 | 11 | |
4d3(2P)5s 3P2 | 3639.0501 | 27 471.891 | 0.132 | 0.131 | 0.990 | 1.75(7) | -0.98 | 12 | |
4d3(2P)5s 3P0 | 3641.3782 | 27 454.328 | 0.037 | 0.034 | 0.936 | 4.59(6) | -1.56 | 20 | |
4d3(4P)5s 3P0 | 4588.9970 | 21 785.149 | 0.033 | 0.028 | 0.836 | 3.67(6) | -1.46 | 23 | |
Residual | 0.146 | ||||||||
4d3(4P)5p
3P
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4d4 5D1 | 2265.4874 | 44 126.956 | 0.025 | 0.04 | 1.612 | 5.66(5) | -2.36 | 28 |
44285.94 cm-1 |
4d4 3P1 | 2624.3286 | 38 093.630 | 0.003 | 0.10 | 31.295 | 1.41(6) | -1.84 | 21 |
4d3(4P)5s 5P1 | 2972.4398 | 33 632.513 | 0.246 | 0.14 | 0.558 | 1.96(6) | -1.59 | 47 | |
4d3(2P)5s 3P1 | 3370.6053 | 29 659.741 | 0.601 | 0.60 | 0.997 | 8.56(6) | -0.84 | 13 | |
Residual | 0.120 | ||||||||
4d3(4P)5p
5D
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4d3(4P)5s 5P1 | 3129.6522 | 31 943.127 | 0.756 | 0.756 | 1.000 | 1.05(8) | -0.814 | 12 |
42596.55 cm-1 | Residual | 0.244 | |||||||
4d3(4P)5p
5D
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4d4 5D2 | 2332.8990 | 42 851.977 | 0.029 | 0.021 | 0.731 | 2.86(6) | -1.93 | 21 |
4d4 3F2 | 2793.6766 | 35 784.573 | 0.029 | 0.047 | 1.649 | 6.30(6) | -1.43 | 19 | |
43290.34 cm-1 | 4d3(4P)5s 5P1 | 3063.1193 | 32 636.911 | 0.120 | 0.132 | 1.103 | 1.76(7) | -0.91 | 14 |
4d3(4P)5s 5P2 | 3080.3475 | 32 454.501 | 0.309 | 0.346 | 1.120 | 4.62(7) | -0.48 | 10 | |
4d3(4P)5s 5P3 | 3128.9145 | 31 950.748 | 0.054 | 0.047 | 0.855 | 6.21(6) | -1.34 | 22 | |
4d4 1D2 | 3222.0580 | 31 027.117 | 0.226 | 0.178 | 0.789 | 2.38(7) | -0.73 | 12 | |
4d3(2D2)5s 3D1 | 4085.3468 | 24 470.818 | 0.030 | 0.031 | 1.034 | 4.16(6) | -1.28 | 18 | |
4d3(2P)5s 1P1 | 4492.9563 | 22 250.809 | 0.072 | 0.066 | 0.921 | 8.83(6) | -0.87 | 14 | |
Residual | 0.130 | ||||||||
4d3(2P)5p
1D
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4d4 5D1 | 2300.2897 | 43 459.407 | 0.019 | 0.013 | 0.685 | 1.93(6) | -2.12 | 15 |
4d4 5D2 | 2315.1745 | 43 180.030 | 0.062 | 0.040 | 0.639 | 5.81(6) | -1.63 | 11 | |
43618.39 cm-1 | 4d4 5D3 | 2334.8014 | 42 817.065 | 0.037 | 0.030 | 0.820 | 4.40(6) | -1.75 | 14 |
4d4 3P2 | 2749.6848 | 36 357.067 | 0.044 | 0.057 | 1.299 | 8.37(6) | -1.32 | 12 | |
4d4 3F3 | 2798.9044 | 35 717.747 | 0.063 | 0.108 | 1.704 | 1.58(7) | -1.03 | 11 | |
4d3(4P)5s 5P1 | 3032.6351 | 32 964.964 | 0.021 | 0.054 | 2.615 | 7.96(6) | -1.26 | 19 | |
4d3(4P)5s 5P2 | 3049.5039 | 32 782.554 | 0.038 | 0.066 | 1.767 | 1.30(7) | -1.04 | 13 | |
4d3(4P)5s 5P3 | 3097.1160 | 32 278.801 | 0.192 | 0.138 | 0.719 | 2.03(7) | -0.84 | 11 | |
4d4 1D2 | 3188.3466 | 31 355.170 | 0.034 | 0.023 | 0.685 | 3.40(6) | -1.59 | 30 | |
4d4 3D2 | 3244.5078 | 30 812.426 | 0.047 | 0.048 | 1.030 | 7.02(6) | -1.26 | 15 | |
4d4 3D1 | 3277.7583 | 30 499.863 | 0.020 | 0.019 | 0.918 | 2.72(6) | -1.66 | 32 | |
4d3(4F)5s 3F3 | 3340.3740 | 29 928.163 | 0.018 | 0.021 | 1.170 | 3.11(6) | -1.59 | 26 | |
4d3(2P)5s 3P1 | 3448.2179 | 28 992.192 | 0.083 | 0.067 | 0.814 | 9.86(6) | -1.06 | 14 | |
Upper level | Lower level |
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BF | A | log (gf) | Unc. | ||
Design. | (Å) | (cm-1) | Calc. | Exp. | Exp/Calc | (s-1) | (% in gf) | ||
4d3(2P)5s 3P2 | 3452.3409 | 28 957.636 | 0.162 | 0.153 | 0.946 | 2.24(7) | -0.70 | 11 | |
4d3(4P)5s 3P2 | 4522.1931 | 22 107.015 | 0.027 | 0.028 | 1.029 | 4.12(6) | -1.20 | 20 | |
Residual | 0.133 | ||||||||
4d3(2P)5p
3D
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4d4 3P2 | 2747.3562 | 36 387.869 | 0.102 | 0.249 | 2.431 | 3.40(7) | -0.94 | 10 |
4d4 3F2 | 2765.9299 | 36 143.428 | 0.186 | 0.076 | 0.409 | 1.04(7) | -1.45 | 12 | |
43649.19 cm-1 | 4d3(4P)5s 5P1 | 3029.8088 | 32 995.766 | 0.028 | 0.138 | 4.942 | 1.88(7) | -1.11 | 11 |
4d3(2P)5s 3P2 | 3448.6696 | 28 988.438 | 0.095 | 0.073 | 0.770 | 1.51(7) | -1.09 | 12 | |
4d3(2P)5s 3P0 | 3450.7619 | 28 970.875 | 0.301 | 0.178 | 0.590 | 2.36(7) | -0.90 | 10 | |
4d3(2D2)5s 3D1 | 4026.3014 | 24 829.673 | 0.046 | 0.049 | 1.063 | 4.09(6) | -1.53 | 23 | |
4d3(2D2)5s 3D2 | 4114.5320 | 24 297.245 | 0.046 | 0.035 | 0.752 | 4.77(6) | -1.44 | 21 | |
4d3(2P)5s 1P1 | 4421.6458 | 22 609.664 | 0.034 | 0.041 | 1.224 | 5.62(6) | -1.31 | 29 | |
Residual | 0.162 | ||||||||
4d3(4P)5p
5D
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4d4 5D2 | 2300.8551 | 43 448.717 | 0.015 | 0.012 | 0.780 | 1.98(6) | -1.96 | 21 |
4d4 5D3 | 2320.2400 | 43 085.752 | 0.033 | 0.028 | 0.834 | 4.73(6) | -1.57 | 16 | |
43887.08 cm-1 | 4d4 5D4 | 2343.2745 | 42 662.255 | 0.010 | 0.012 | 1.220 | 2.09(6) | -1.92 | 29 |
4d4 3P2 | 2729.5123 | 36 625.754 | 0.014 | 0.013 | 0.925 | 2.20(6) | -1.77 | 24 | |
4d4 3F4 | 2810.7918 | 35 566.705 | 0.088 | 0.122 | 1.384 | 2.48(7) | -0.69 | 15 | |
4d3(4P)5s 5P2 | 3024.7316 | 33 051.241 | 0.477 | 0.401 | 0.841 | 6.86(7) | -0.18 | 15 | |
4d3(4P)5s 5P3 | 3071.5463 | 32 547.488 | 0.262 | 0.305 | 1.165 | 5.23(7) | -0.29 | 15 | |
4d4 3D3 | 3242.4077 | 30 832.382 | 0.011 | 0.018 | 1.656 | 3.08(6) | -1.47 | 49 | |
4d3(4P)5s 3P2 | 4467.8849 | 22 375.702 | 0.016 | 0.015 | 0.949 | 2.62(6) | -1.26 | 22 | |
Residual | 0.074 | ||||||||
4d3(4P)5p
5D
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4d4 5D2 | 2291.3844 | 43 628.304 | 0.023 | 0.014 | 0.609 | 2.18(6) | -2.29 | 26 |
4d4 3F2 | 2734.3521 | 36 560.900 | 0.083 | 0.124 | 1.487 | 1.94(7) | -1.19 | 17 | |
44066.67 cm-1 | 4d3(4P)5s 5P1 | 2991.9493 | 33 413.238 | 0.379 | 0.276 | 0.727 | 4.31(7) | -0.76 | 19 |
4d3(2P)5s 3P1 | 3395.7224 | 29 440.466 | 0.131 | 0.065 | 0.498 | 1.02(7) | -1.28 | 22 | |
4d3(2P)5s 3P2 | 3399.7112 | 29 405.910 | 0.154 | 0.291 | 1.894 | 4.55(7) | -0.63 | 17 | |
Residual | 0.230 | ||||||||
4d3(2P)5p
3D
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4d4 5D3 | 2265.6748 | 44 123.277 | 0.059 | 0.072 | 1.217 | 1.10(7) | -1.37 | 13 |
4d4 3F2 | 2671.6567 | 37 418.838 | 0.028 | 0.016 | 0.582 | 9.32(6) | -1.30 | 14 | |
44924.60 cm-1 | 4d4 3F3 | 2700.1527 | 37 023.959 | 0.211 | 0.250 | 1.187 | 3.82(7) | -0.68 | 12 |
4d3(4P)5s 5P1 | 2917.0516 | 34 271.176 | 0.186 | 0.225 | 1.206 | 3.43(7) | -0.66 | 13 | |
4d3(4F)5s 3F2 | 3179.2265 | 31 445.143 | 0.021 | 0.025 | 1.200 | 3.86(6) | -1.53 | 65 | |
4d3(2P)5s 3P1 | 3299.5510 | 30 298.404 | 0.098 | 0.055 | 0.563 | 8.47(6) | -1.16 | 17 | |
4d3(2P)5s 3P2 | 3303.3216 | 30 263.848 | 0.114 | 0.093 | 0.819 | 1.43(7) | -0.93 | 15 | |
4d3(2D2)5s 3D2 | 3909.3197 | 25 572.655 | 0.022 | 0.008 | 0.361 | 1.22(6) | -1.85 | 32 | |
4d3(2P)5s 1P1 | 4185.5335 | 23 885.074 | 0.048 | 0.042 | 0.890 | 6.46(6) | -1.07 | 32 | |
Residual | 0.212 | ||||||||
4d3(4P)5p
5D
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4d4 5D3 | 2263.3106 | 44 169.386 | 0.014 | 0.010 | 0.709 | 1.85(6) | -1.89 | 20 |
4d4 5D4 | 2285.2235 | 43 745.889 | 0.066 | 0.054 | 0.813 | 1.04(7) | -1.14 | 12 | |
44970.71 cm-1 | 4d3(4P)5s 5P3 | 2972.5710 | 33 631.122 | 0.890 | 0.907 | 1.020 | 1.75(8) | 0.32 | 10 |
4d3(4F)5s 3F4 | 3193.4495 | 31 305.026 | 0.008 | 0.006 | 0.857 | 1.24(6) | -1.77 | 52 | |
Residual | 0.023 | ||||||||
4d3(2P)5p
3D
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4d4 5D4 | 2242.5800 | 44 577.650 | 0.017 | 0.055 | 3.162 | 1.20(7) | -1.20 | 10 |
4d4 3F4 | 2667.1467 | 37 482.100 | 0.068 | 0.157 | 2.300 | 3.41(7) | -0.59 | 9 | |
45802.47 cm-1 | 4d4 3H4 | 2754.5496 | 36 292.869 | 0.123 | 0.105 | 0.852 | 2.27(7) | -0.74 | 11 |
4d4 1D2 | 2980.7132 | 33 539.252 | 0.217 | 0.251 | 1.158 | 5.46(7) | -0.29 | 11 | |
4d4 3D2 | 3029.7413 | 32 996.508 | 0.120 | 0.087 | 0.722 | 1.88(7) | -0.74 | 16 | |
4d3(4F)5s 3F4 | 3110.7976 | 32 136.787 | 0.029 | 0.021 | 0.730 | 4.62(6) | -1.33 | 28 | |
4d3(4F)5s 3F3 | 3113.1748 | 32 112.245 | 0.012 | 0.029 | 2.370 | 6.32(6) | -1.19 | 21 | |
4d3(2G)5s 3G3 | 3304.7036 | 30 251.221 | 0.161 | 0.067 | 0.415 | 1.46(7) | -0.78 | 14 | |
4d3(2G)5s 3G4 | 3348.7755 | 29 853.103 | 0.074 | 0.050 | 0.675 | 1.08(7) | -0.90 | 14 | |
4d3(2H)5s 3H4 | 3528.4778 | 28 332.703 | 0.078 | 0.078 | 1.002 | 1.70(7) | -0.66 | 17 | |
Residual | 0.101 | ||||||||
4d3(2H)5p
3H
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4d4 3H5 | 2566.0734 | 38 958.386 | 0.021 | 0.013 | 0.621 | 3.06(6) | -1.41 | 14 |
4d4 3H6 | 2590.9428 | 38 584.448 | 0.358 | 0.478 | 1.333 | 1.14(8) | 0.17 | 11 | |
48770.84 cm-1 | 4d4 3G5 | 2641.0561 | 37 852.364 | 0.031 | 0.042 | 1.362 | 1.01(7) | -0.86 | 12 |
4d3(2G)5s 3G5 | 3055.5159 | 32 718.166 | 0.257 | 0.095 | 0.368 | 2.25(7) | -0.39 | 24 | |
4d3(2H)5s 3H5 | 3175.8669 | 31 478.359 | 0.246 | 0.252 | 1.024 | 5.99(7) | 0.07 | 17 | |
4d3(2H)5s 3H6 | 3189.2788 | 31 345.949 | 0.086 | 0.120 | 1.393 | 2.86(7) | -0.25 | 20 | |
Residual | 0.001 |
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