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Table 7:

Transitions of gauche-n-propyl cyanide, employed in the present fits, their frequencies (MHz), uncertainties Unc. (kHz), and residuals O-C (kHz) between frequencies measured in the laboratory and those calculated from the final spectroscopic parameters. Unresolved asymmetry splitting (two transitions having the same Ka and the same transition frequency) has been treated as intensity-weighted average of the two lines.
J', Ka', Kc' - J'', Ka'', Kc'' Frequency Unc. O-C
2, 0, 2 - 1, 0, 1 11912.654 10 -18
2, 1, 2 - 1, 1, 1 11384.045 10 -0
2, 1, 1 - 1, 1, 0 12508.374 10 -10
3, 0, 3 - 2, 0, 2 17785.949 10 6
3, 1, 3 - 2, 1, 2 17055.610 5 1
2, 1, 2 - 1, 0, 1 18176.781 5 1
4, 1, 3 - 4, 0, 4 10286.601 5 0
5, 1, 4 - 5, 0, 5 12167.868 5 -3
6, 1, 5 - 6, 0, 6 14609.404 5 1
7, 1, 6 - 7, 0, 7 17634.822 5 1
2, 2, 1 - 2, 1, 2 22064.261 5 0
24, 3, 21 - 25, 2, 24 5073.952 5 0
10, 3, 7 - 9, 4, 6 12670.827 5 -2
11, 3, 9 - 10, 4, 6 16546.819 5 -3
28, 3, 26 - 27, 4, 23 19891.929 5 1
36, 4, 32 - 37, 3, 35 19547.899 5 1
13, 4, 10 - 12, 5, 7 15362.409 5 0
38, 4, 35 - 37, 5, 32 9991.617 5 0
39, 4, 36 - 38, 5, 33 5311.217 5 1
15, 5, 10 - 14, 6, 9 13597.769 5 1
12, 7, 6 - 13, 6, 7 13549.701 5 -1
12, 7, 5 - 13, 6, 8 13551.095 5 5
13, 7, 7 - 14, 6, 8 7398.401 5 -2
13, 7, 6 - 14, 6, 9 7401.855 5 4
15, 8, 8 - 16, 7, 9 9498.238 5 -4
15, 8, 7 - 16, 7, 10 9498.794 5 -5
19, 7, 12 - 18, 8, 11 9123.186 5 -1
19, 7, 13 - 18, 8, 10 9116.781 5 -1
20, 7, 14 - 19, 8, 11 15398.422 5 0
22, 8, 14 - 21, 9, 13 13221.090 5 -0
22, 8, 15 - 21, 9, 12 13218.792 5 -2
23, 8, 15 - 22, 9, 14 19511.211 5 2
23, 8, 16 - 22, 9, 13 19506.528 5 0
19, 10, 10 - 20, 9, 11 13681.725 5 -1
19, 10, 9 - 20, 9, 12 13681.725 5 -1
25, 9, 17 - 24, 10, 14 17310.401 5 -6
25, 9, 16 - 24, 10, 15 17311.214 5 2
26, 9, 18 - 25, 10, 15 23599.302 5 2
26, 9, 17 - 25, 10, 16 23600.945 5 11
28, 10, 19 - 27, 11, 16 21388.390 5 -9
28, 10, 18 - 27, 11, 17 21388.670 5 -6
26, 13, 14 - 27, 12, 15 13813.369 5 -3
26, 13, 13 - 27, 12, 16 13813.369 5 -3
22, 4, 18 - 22, 4, 19 25543.715 5 -1
25, 5, 20 - 25, 5, 21 16254.957 5 2
26, 5, 21 - 26, 5, 22 21090.090 5 -1
30, 6, 24 - 30, 6, 25 16246.388 5 1
31, 6, 25 - 31, 6, 26 21145.902 5 1
34, 7, 27 - 34, 7, 28 11727.780 5 -2
36, 7, 29 - 36, 7, 30 20572.880 5 -2
37, 7, 30 - 37, 7, 31 26237.933 5 4
39, 8, 31 - 39, 8, 32 11013.037 5 -2
25, 5, 21 - 24, 4, 20 182990.23 50 19
26, 6, 21 - 25, 6, 20 157628.25 50 16
26, 7, 19 - 25, 7, 18 157477.90 50 8
26, 10, 17 - 25, 10, 16 156296.53 50 -59
26, 10, 16 - 25, 10, 15 156296.53 50 -59
26, 11, 16 - 25, 11, 15 156141.79 50 65
26, 11, 15 - 25, 11, 14 156141.79 50 65
26, 12, 15 - 25, 12, 14 156032.20 50 -22
26, 12, 14 - 25, 12, 13 156032.20 50 -22
26, 13, 14 - 25, 13, 13 155954.49 50 -56
26, 13, 13 - 25, 13, 12 155954.49 50 -56
26, 14, 13 - 25, 14, 12 155900.13 50 -0
26, 14, 12 - 25, 14, 11 155900.13 50 -0
26, 15, 12 - 25, 15, 11 155863.29 50 -10
26, 15, 11 - 25, 15, 10 155863.29 50 -10
26, 17, 10 - 25, 17, 9 155827.91 50 -33
26, 17, 9 - 25, 17, 8 155827.91 50 -33
26, 18, 9 - 25, 18, 8 155824.64 50 -20
26, 18, 8 - 25, 18, 7 155824.64 50 -20
26, 19, 8 - 25, 19, 7 155828.81 50 -17
26, 19, 7 - 25, 19, 6 155828.81 50 -17
28, 1, 27 - 27, 1, 26 157495.25 50 -33
28, 2, 27 - 27, 1, 26 157503.23 50 -51
28, 1, 27 - 27, 2, 26 157482.64 50 46
28, 2, 27 - 27, 2, 26 157490.60 50 8
29, 5, 25 - 28, 4, 24 189805.28 50 48
30, 4, 27 - 29, 3, 26 178167.69 50 31
30, 4, 26 - 29, 4, 25 182703.13 50 -23
30, 5, 26 - 29, 4, 25 192210.43 50 32
30, 7, 23 - 29, 7, 22 182961.27 50 -29
31, 2, 29 - 30, 2, 28 177803.90 50 -13
31, 3, 29 - 30, 2, 28 177857.94 50 -1
31, 2, 29 - 30, 3, 28 177721.22 50 6
31, 3, 29 - 30, 3, 28 177775.23 50 -12
31, 3, 28 - 30, 3, 27 182248.22 50 -22
31, 4, 28 - 30, 3, 27 183077.55 50 26
31, 3, 28 - 30, 4, 27 181050.65 50 36
31, 4, 27 - 30, 5, 26 178318.43 50 156
31, 5, 26 - 30, 5, 25 192803.61 50 6
31, 7, 25 - 30, 7, 24 188156.51 50 -20
31, 7, 24 - 30, 7, 23 189515.12 50 -74
31, 8, 23 - 30, 8, 22 187858.13 50 9
32, 2, 30 - 31, 2, 29 183183.36 50 18
32, 3, 30 - 31, 2, 29 183218.50 50 28
32, 2, 30 - 31, 3, 29 183129.35 50 37
32, 3, 30 - 31, 3, 29 183164.45 50 6
32, 4, 29 - 31, 3, 28 188119.54 50 -5
32, 4, 28 - 31, 4, 27 192927.96 50 -13
32, 4, 28 - 31, 5, 27 185714.09 50 6
32, 10, 23 - 31, 10, 22 192852.63 50 -4
32, 10, 22 - 31, 10, 21 192854.42 50 -4
32, 12, 21 - 31, 12, 20 192320.23 50 5
32, 12, 20 - 31, 12, 19 192320.23 50 5
32, 13, 20 - 31, 13, 19 192158.76 50 -19
32, 13, 19 - 31, 13, 18 192158.76 50 -19
32, 14, 19 - 31, 14, 18 192040.62 50 14
32, 14, 18 - 31, 14, 17 192040.62 50 14
33, 2, 31 - 32, 2, 30 188564.34 50 -33
33, 3, 31 - 32, 2, 30 188587.13 50 13
33, 2, 31 - 32, 3, 30 188529.24 50 -2
33, 3, 31 - 32, 3, 30 188551.94 50 -47
33, 3, 30 - 32, 3, 29 192871.17 50 -3
33, 4, 30 - 32, 3, 29 193259.00 50 18
33, 3, 30 - 32, 4, 29 192301.88 50 -16
33, 4, 30 - 32, 4, 29 192689.70 50 -5
33, 4, 29 - 32, 5, 28 192663.51 50 12
34, 2, 32 - 33, 2, 31 193946.21 50 -59
34, 3, 32 - 33, 2, 31 193960.95 50 14
34, 2, 32 - 33, 3, 31 193923.55 50 26
34, 3, 32 - 33, 3, 31 193938.16 50 -32
34, 6, 28 - 33, 6, 27 212120.06 50 3
35, 6, 29 - 34, 6, 28 218287.17 50 -26
35, 7, 29 - 34, 7, 28 212483.75 50 16
35, 8, 28 - 34, 8, 27 212458.29 50 -13
35, 9, 27 - 34, 9, 26 211828.06 50 142
35, 9, 26 - 34, 9, 25 211938.01 50 7
36, 4, 32 - 35, 5, 31 211527.01 50 14
36, 10, 27 - 35, 10, 26 217402.38 50 -15
36, 10, 26 - 35, 10, 25 217418.12 50 -2
36, 11, 26 - 35, 11, 25 216940.59 50 -30
36, 11, 25 - 35, 11, 24 216941.74 50 33
36, 12, 25 - 35, 12, 24 216609.17 50 -33
36, 12, 24 - 35, 12, 23 216609.17 50 -33
36, 13, 24 - 35, 13, 23 216367.23 50 -1
36, 13, 23 - 35, 13, 22 216367.23 50 -1
36, 14, 23 - 35, 14, 22 216188.17 50 23
36, 14, 22 - 35, 14, 21 216188.17 50 23
36, 16, 21 - 35, 16, 20 215956.57 50 -26
36, 16, 20 - 35, 16, 19 215956.57 50 -26
36, 17, 20 - 35, 17, 19 215885.18 50 -12
36, 17, 19 - 35, 17, 18 215885.18 50 -12
36, 18, 19 - 35, 18, 18 215835.30 50 9
36, 18, 18 - 35, 18, 17 215835.30 50 9
36, 20, 17 - 35, 20, 16 215784.95 50 23
36, 20, 16 - 35, 20, 15 215784.95 50 23
36, 21, 16 - 35, 21, 15 215779.22 50 45
36, 21, 15 - 35, 21, 14 215779.22 50 45
36, 22, 15 - 35, 22, 14 215783.85 50 5
36, 22, 14 - 35, 22, 13 215783.85 50 5
36, 23, 14 - 35, 23, 13 215797.53 50 -19
36, 23, 13 - 35, 23, 12 215797.53 50 -19
36, 24, 13 - 35, 24, 12 215819.22 50 36
36, 24, 12 - 35, 24, 11 215819.22 50 36
36, 25, 12 - 35, 25, 11 215847.81 50 -52
36, 25, 11 - 35, 25, 10 215847.81 50 -52
36, 26, 11 - 35, 26, 10 215882.85 50 -12
36, 26, 10 - 35, 26, 9 215882.85 50 -12
36, 27, 10 - 35, 27, 9 215923.60 50 10
36, 27, 9 - 35, 27, 8 215923.60 50 10
36, 28, 9 - 35, 28, 8 215969.54 50 -15
36, 28, 8 - 35, 28, 7 215969.54 50 -15
36, 32, 5 - 35, 32, 4 216198.45 50 4
36, 32, 4 - 35, 32, 3 216198.45 50 4
37, 3, 34 - 36, 3, 33 214265.30 50 -8
37, 3, 34 - 36, 4, 33 214147.29 50 -26
37, 4, 34 - 36, 4, 33 214225.81 50 -13
38, 1, 37 - 37, 2, 36 211401.39 50 59
38, 3, 36 - 37, 2, 35 215476.23 50 36
38, 2, 36 - 37, 3, 35 215469.85 50 -35
38, 3, 35 - 37, 3, 34 219628.21 50 19
38, 3, 35 - 37, 4, 34 219549.67 50 -13
38, 4, 35 - 37, 4, 34 219601.64 50 -40
39, 0, 39 - 38, 1, 38 212743.02 50 6
39, 2, 37 - 38, 2, 36 220854.26 50 -8
39, 3, 37 - 38, 2, 36 220855.81 50 -18
39, 2, 37 - 38, 3, 36 220851.79 50 -24
39, 3, 37 - 38, 3, 36 220853.34 50 -33
40, 0, 40 - 39, 1, 39 218129.30 50 18
47, 14, 34 - 46, 14, 33 282874.18 50 42
47, 17, 31 - 46, 17, 30 282070.21 50 4
47, 17, 30 - 46, 17, 29 282070.21 50 4
47, 19, 29 - 46, 19, 28 281801.94 50 20
47, 19, 28 - 46, 19, 27 281801.94 50 20
47, 20, 28 - 46, 20, 27 281716.83 50 33
47, 20, 27 - 46, 20, 26 281716.83 50 33
47, 21, 27 - 46, 21, 26 281656.67 50 10
47, 21, 26 - 46, 21, 25 281656.67 50 10
47, 22, 26 - 46, 22, 25 281617.41 50 -44
47, 22, 25 - 46, 22, 24 281617.41 50 -44
47, 23, 25 - 46, 23, 24 281596.02 50 -16
47, 23, 24 - 46, 23, 23 281596.02 50 -16
47, 24, 24 - 46, 24, 23 281589.94 50 8
47, 24, 23 - 46, 24, 22 281589.94 50 8
47, 25, 23 - 46, 25, 22 281597.15 50 -18
47, 25, 22 - 46, 25, 21 281597.15 50 -18
47, 26, 22 - 46, 26, 21 281616.14 50 -10
47, 26, 21 - 46, 26, 20 281616.14 50 -10
47, 27, 21 - 46, 27, 20 281645.57 50 -9
47, 27, 20 - 46, 27, 19 281645.57 50 -9
47, 28, 20 - 46, 28, 19 281684.43 50 48
47, 28, 19 - 46, 28, 18 281684.43 50 48
47, 29, 19 - 46, 29, 18 281731.64 50 -30
47, 29, 18 - 46, 29, 17 281731.64 50 -30
47, 30, 18 - 46, 30, 17 281786.66 50 -36
47, 30, 17 - 46, 30, 16 281786.66 50 -36
47, 31, 17 - 46, 31, 16 281848.86 50 31
47, 31, 16 - 46, 31, 15 281848.86 50 31
47, 33, 15 - 46, 33, 14 281992.38 50 34
47, 33, 14 - 46, 33, 13 281992.38 50 34
47, 34, 14 - 46, 34, 13 282072.85 50 -22
47, 34, 13 - 46, 34, 12 282072.85 50 -22
48, 5, 43 - 47, 5, 42 281724.06 50 0
48, 6, 43 - 47, 6, 42 281635.78 50 -33

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