Rotational excitation of ortho-H2O by para-H2 (j2 = 0, 2, 4, 6, 8) at high temperature

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Volume 497 / No 3 (April III 2009)

A&A, 497 3 (2009) 911-925

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Table 2:

Rotational (de)excitation cross-sections (in $\AA^2$ ) of o-H₂O calculated with different basis sets: (1) a complete B(6,2) basis set, (2) a B^*(6,4)[all, all, 5] basis set with an incomplete ladder in j₂=4, (3) a B^*(9,4)[10, 10, 5] basis set with incomplete ladders for j₂=0,2,4. The transitions are labelled by the quantum numbers $j_1 k_{\rm a} k_{\rm c} \rightarrow j'_1 k'_{\rm a} k'_{\rm c}$ (j₂-j'₂) where primes are final states.
Total energy (cm^-1)	Transition	B(6,2)	B^*(6,4)[all, all, 5]	B^*(9,4)[10, 10, 5]	Difference
429.5	1₀₁ $\rightarrow$ 1₁₀ (0-2)	0.021	0.025		16%
	1₀₁ $\rightarrow$ 1₁₀ (0-0)	3.890	3.856		0,8%
	3₃₀ $\rightarrow$ 1₁₀ (0-2)	0.443	0.500		11%
	3₃₀ $\rightarrow$ 1₁₀ (0-0)	0.106	0.102		4%
681.1	1₀₁ $\rightarrow$ 1₁₀ (0-2)		0.176	0.175	0.5%
	1₀₁ $\rightarrow$ 1₁₀ (0-0)		4.3480	4.3489	0.02%
	3₃₀ $\rightarrow$ 1₁₀ (0-2)		0.9760	0.9773	0.1%
	3₃₀ $\rightarrow$ 1₁₀ (0-0)		0.1488	0.1481	0.4%
834.9	1₀₁ $\rightarrow$ 1₁₀ (0-2)	0.268	0.318		16%
	1₀₁ $\rightarrow$ 1₁₀ (0-0)	4.454	4.412		1%
	3₃₀ $\rightarrow$ 1₁₀ (0-2)	0.919	0.980		6%
	3₃₀ $\rightarrow$ 1₁₀ (0-0)	0.194	0.186		4%

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