Table 3:
Comparison of present calculations of the transition wavenumbers of B-X, C+-X, and C--X electronic band systems of HD with the high-resolution experimental determinations of Hinnen et al. (1995) (o1-c) and Dabrowski & Herzberg (1976) (o2-c).
Band system |
v' |
J' |
v'' |
J'' |
 |
o1-c |
o2-c |
|
|
|
|
|
(cm-1) |
(cm-1) |
(cm-1) |
B-X |
12 |
0 |
0 |
1 |
102 397.35 |
-2.48 |
-1.99 |
|
12 |
1 |
0 |
0 |
102 506.03 |
-2.47 |
-3.13 |
|
12 |
1 |
0 |
2 |
102 238.91 |
-2.39 |
-2.11 |
|
12 |
2 |
0 |
1 |
102 455.64 |
-2.57 |
-2.17 |
|
12 |
2 |
0 |
3 |
102 012.55 |
-2.70 |
-2.40 |
|
12 |
3 |
0 |
2 |
102 335.82 |
-2.96 |
-2.66 |
|
13 |
0 |
0 |
1 |
103 250.31 |
-2.32 |
-2.01 |
|
13 |
1 |
0 |
0 |
103 358.80 |
-2.76 |
-2.62 |
|
13 |
1 |
0 |
2 |
103 091.68 |
-2.37 |
-1.82 |
|
13 |
2 |
0 |
1 |
103 308.38 |
-2.41 |
-2.12 |
|
13 |
2 |
0 |
3 |
102 865.29 |
-2.50 |
-2.15 |
|
13 |
3 |
0 |
2 |
103 192.07 |
-0.42 |
-0.45 |
|
13 |
3 |
0 |
4 |
102 575.89 |
-0.42 |
-0.33 |
|
13 |
4 |
0 |
3 |
102 987.85 |
-2.75 |
-2.71 |
|
13 |
4 |
0 |
5 |
102 202.72 |
-2.60 |
-2.76 |
|
13 |
5 |
0 |
4 |
102 733.46 |
-7.79 |
-7.51 |
|
13 |
6 |
0 |
5 |
102 410.93 |
-1.62 |
-1.72 |
|
14 |
0 |
0 |
1 |
104 081.13 |
-2.39 |
-2.36 |
|
14 |
1 |
0 |
0 |
104 188.72 |
-2.43 |
-2.24 |
|
14 |
1 |
0 |
2 |
103 921.60 |
-2.40 |
-1.99 |
|
14 |
2 |
0 |
1 |
104 136.13 |
-2.52 |
-2.48 |
|
14 |
2 |
0 |
3 |
103 693.04 |
-2.47 |
-2.21 |
|
14 |
3 |
0 |
2 |
104 013.05 |
-2.50 |
-2.33 |
|
14 |
3 |
0 |
4 |
103 396.87 |
-2.44 |
-2.34 |
|
14 |
4 |
0 |
3 |
103 820.63 |
-2.67 |
-2.54 |
|
14 |
4 |
0 |
5 |
103 035.50 |
-2.66 |
-2.37 |
|
14 |
5 |
0 |
4 |
103 560.13 |
-3.09 |
-2.85 |
|
16 |
0 |
0 |
1 |
105 677.68 |
-2.55 |
-2.71 |
|
16 |
1 |
0 |
0 |
105 784.26 |
-2.53 |
-2.72 |
|
16 |
1 |
0 |
2 |
105 517.14 |
-2.47 |
-2.44 |
|
16 |
2 |
0 |
1 |
105 729.66 |
-2.54 |
-1.77 |
|
16 |
2 |
0 |
3 |
105 286.57 |
-2.51 |
-2.31 |
|
16 |
3 |
0 |
2 |
105 603.59 |
-2.47 |
-3.06 |
|
16 |
4 |
0 |
3 |
105 407.25 |
-2.59 |
-2.45 |
|
17 |
0 |
0 |
1 |
106 444.10 |
-3.79 |
-3.94 |
|
17 |
1 |
0 |
0 |
106 549.74 |
-3.59 |
-4.06 |
|
17 |
1 |
0 |
2 |
106 282.62 |
-3.58 |
-4.08 |
|
17 |
2 |
0 |
1 |
106 493.55 |
-3.44 |
-2.61 |
|
17 |
2 |
0 |
3 |
106 050.46 |
-3.41 |
- |
|
17 |
3 |
0 |
2 |
106 365.41 |
-3.22 |
-3.40 |
|
17 |
3 |
0 |
4 |
105 749.23 |
-3.14 |
-3.48 |
|
17 |
4 |
0 |
3 |
106 166.55 |
-4.25 |
-3.62 |
|
18 |
0 |
0 |
1 |
107 189.71 |
-2.33 |
-2.55 |
|
18 |
1 |
0 |
0 |
107 295.36 |
-2.35 |
-2.55 |
|
18 |
1 |
0 |
2 |
107 028.24 |
-2.30 |
-2.47 |
|
18 |
2 |
0 |
1 |
107 238.92 |
-2.36 |
-2.58 |
|
18 |
2 |
0 |
3 |
106 795.83 |
-2.33 |
-2.61 |
|
18 |
3 |
0 |
2 |
107 110.15 |
-2.24 |
-2.49 |
|
18 |
3 |
0 |
4 |
106 493.97 |
-2.27 |
-3.03 |
|
18 |
4 |
0 |
3 |
106 910.37 |
-2.23 |
-2.52 |
|
18 |
5 |
0 |
4 |
106 641.37 |
-0.17 |
-0.32 |
|
18 |
6 |
0 |
5 |
106 307.99 |
-1.99 |
-2.65 |
|
19 |
0 |
0 |
1 |
107 914.87 |
-2.50 |
-3.04 |
|
19 |
1 |
0 |
0 |
108 019.75 |
-2.52 |
-3.10 |
|
19 |
1 |
0 |
2 |
107 752.63 |
-2.44 |
-2.94 |
|
19 |
2 |
0 |
1 |
107 961.85 |
-2.49 |
-2.96 |
|
19 |
2 |
0 |
3 |
107 518.76 |
-2.56 |
-2.96 |
|
19 |
3 |
0 |
2 |
107 830.98 |
-2.45 |
-2.93 |
|
19 |
3 |
0 |
4 |
107 214.80 |
-2.43 |
-2.80 |
|
19 |
4 |
0 |
3 |
107 628.38 |
-2.53 |
-2.98 |
|
19 |
5 |
0 |
4 |
107 355.37 |
-2.34 |
-2.85 |
C+-X |
2 |
1 |
0 |
0 |
103 202.63 |
-0.55 |
-0.50 |
|
2 |
1 |
0 |
2 |
102 935.51 |
-0.65 |
-0.83 |
|
2 |
2 |
0 |
1 |
103 197.39 |
-0.57 |
-1.44 |
|
2 |
2 |
0 |
3 |
102 754.30 |
-0.71 |
-0.32 |
|
2 |
3 |
0 |
2 |
103 141.13 |
-0.85 |
-0.53 |
|
2 |
3 |
0 |
4 |
102 524.95 |
-0.80 |
-0.73 |
|
2 |
4 |
0 |
3 |
103 057.40 |
-0.76 |
-0.71 |
|
2 |
4 |
0 |
5 |
102 272.27 |
-0.61 |
-0.56 |
|
2 |
5 |
0 |
4 |
102 910.03 |
-0.58 |
0.05 |
|
2 |
5 |
0 |
6 |
101 960.78 |
-0.02 |
-0.38 |
|
2 |
6 |
0 |
5 |
102 720.33 |
-0.55 |
-0.52 |
|
2 |
7 |
0 |
6 |
102 486.54 |
-0.25 |
-0.39 |
|
4 |
1 |
0 |
0 |
106 732.53 |
-0.95 |
-0.94 |
|
4 |
1 |
0 |
2 |
106 465.41 |
-0.90 |
-1.26 |
|
4 |
2 |
0 |
1 |
106 720.87 |
-0.95 |
-1.03 |
|
4 |
2 |
0 |
3 |
106 277.78 |
-0.95 |
-1.03 |
|
4 |
3 |
0 |
2 |
106 658.13 |
-0.92 |
-0.95 |
|
4 |
3 |
0 |
4 |
106 041.95 |
-0.85 |
-0.53 |
|
4 |
4 |
0 |
3 |
106 544.56 |
-0.98 |
-1.13 |
|
4 |
4 |
0 |
5 |
105 759.43 |
-0.88 |
-1.21 |
|
4 |
5 |
0 |
4 |
106 380.08 |
-0.90 |
-1.16 |
|
4 |
6 |
0 |
5 |
106 163.43 |
-0.01 |
-0.50 |
|
5 |
4 |
0 |
5 |
107 357.78 |
-0.90 |
-1.06 |
|
5 |
5 |
0 |
4 |
107 963.09 |
-1.22 |
-1.98 |
C--X |
2 |
1 |
0 |
1 |
103 112.91 |
-0.57 |
-1.17 |
|
2 |
2 |
0 |
2 |
103 018.50 |
-0.65 |
0.22 |
|
2 |
3 |
0 |
3 |
102 877.89 |
-0.72 |
-0.57 |
|
2 |
4 |
0 |
4 |
102 691.86 |
-0.53 |
-0.36 |
|
2 |
5 |
0 |
5 |
102 462.06 |
-0.52 |
-0.37 |
|
2 |
6 |
0 |
6 |
102 189.52 |
-0.07 |
-0.40 |
|
4 |
1 |
0 |
1 |
106 642.14 |
-0.94 |
-1.09 |
|
4 |
2 |
0 |
2 |
106 539.88 |
-0.90 |
-1.00 |
|
4 |
3 |
0 |
3 |
106 387.52 |
-0.96 |
-1.00 |
|
4 |
4 |
0 |
4 |
106 185.90 |
-0.75 |
-1.21 |
|
4 |
5 |
0 |
5 |
105 936.72 |
-0.78 |
-1.19 |
|
5 |
4 |
0 |
4 |
107 787.23 |
-0.83 |
-1.40 |
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