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A 180-level BPRM calculation was used for the resonance energy region (up to 9.95 Ryd), with a maximum of 1104 channels in each partial wave. In order for this calculation to be computational feasable, the number of continuum terms was the minimum required to span this energy range: only five per channel, resulting in collisional Hamiltonian matrices of maximum order 6164. The purpose of this calculation was to obtain accurate collision strengths in the low-energy resonance region, and since resonances are important only for low partial waves the expansion was truncated at J=6.
A 31-level BPRM calculation was used to top-up both the energy and the partial-wave expansion, in order to calculate converged collision strengths to a high enough energy for collision rates to be obtained over a realistic temperature range. The 31-level calculation had only 158 channels, so 30 continuum terms per channel could be included and the partial-waves calculated up to J=56, enabling converged collision strengths to be calculated for the transitions 3s23p5-3s3p6, 3s23p5-3s23p43d and 3s3p6-3s23p43d (i.e. up to the lowest 31 levels), and the energy range extended from 9.95 to 600 Ryd.
Table 1 lists the energies of the lowest 31 levels calculated from
the wavefunction used in the 181-level BPRM calculation,
and compares with NIST reference data.
Table 2 compares the oscillator strengths obtained using the 181-level BPRM
wavefunction with those of Bhatia & Doshek (1995).
The oscillator strengths from the two calculations are qualitatively similar but
not in very good agreement.
However, our results are much closer to a recent experiment by Träbert (1996)
for the lifetime and branching ratio of the 3s3p6 2S
level
(Table 3).
i | State | J | Present | Expt |
1 |
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.0000 | .0000 |
2 |
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.1346 | .1429 |
3 |
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2.631 | 2.636 |
4 |
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3.581 | 3.542 |
5 |
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3.582 | 3.542 |
6 |
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3.591 | 3.554 |
7 |
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3.603 | 3.568 |
8 |
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3.863 | 3.806 |
9 |
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3.875 | |
10 |
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3.906 | 3.853 |
11 |
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3.938 | 3.889 |
12 |
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3.947 | 3.903 |
13 |
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3.952 | 3.936 |
14 |
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4.014 | 3.962 |
15 |
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4.015 | 3.961 |
16 |
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4.057 | |
17 |
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4.079 | 4.026 |
18 |
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4.081 | 4.017 |
19 |
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4.097 | |
20 |
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4.172 | 4.108 |
21 |
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4.173 | 4.111 |
22 |
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4.195 | 4.126 |
23 |
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4.460 | |
24 |
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4.495 | 4.429 |
25 |
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4.735 | 4.664 |
26 |
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4.774 | |
27 |
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5.059 | 4.938 |
28 |
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5.255 | 5.141 |
29 |
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5.307 | 5.194 |
30 |
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5.351 | 5.221 |
31 |
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5.466 | 5.342 |
i-i' | Ji' | BD | Present | A, s-1 |
1-3 | 1/2 | 0.0716 | 0.1027 | 2.854E9 |
1-4 | 5/2 | 0.71E-4 | 2.08E-4 | 3.504E6 |
1-6 | 3/2 | 2.06E-4 | 2.02E-4 | 5.281E6 |
1-7 | 1/2 | 9.14E-5 | 5.59E-5 | 2.926E6 |
1-9 | 1/2 | 2.68E-3 | 8.12E-4 | 4.954E7 |
1-11 | 5/2 | 1.24E-3 | 1.49E-3 | 3.031E7 |
1-12 | 3/2 | 19.7E-3 | 9.03E-3 | 2.783E8 |
1-13 | 3/2 | 5.65E-5 | 2.10E-3 | 6.651E7 |
1-14 | 1/2 | 2.25E-3 | 3.56E-3 | 2.325E8 |
1-15 | 3/2 | 9.56E-3 | 4.85E-3 | 1.557E8 |
1-16 | 3/2 | 28.2E-4 | 4.17E-4 | 1.397E7 |
1-17 | 5/2 | 6.40E-3 | 4.64E-3 | 1.017E8 |
1-19 | 5/2 | 15.9E-3 | 3.67E-3 | 8.114E7 |
1-22 | 5/2 | 11.1E-4 | 6.82E-4 | 1.579E7 |
1-23 | 5/2 | 3.66E-3 | 4.60E-3 | 1.206E8 |
1-25 | 3/2 | 0.0131 | 0.0100 | 4.441E8 |
1-26 | 5/2 | 0.58E-3 | 2.45E-3 | 7.356E7 |
1-27 | 1/2 | 1.940 | 1.312 | 1.338E11 |
1-28 | 3/2 | 3.788 | 2.817 | 1.542E11 |
1-29 | 1/2 | 0.1863 | 0.3693 | 4.260E10 |
1-30 | 5/2 | 6.462 | 5.128 | 1.941E11 |
1-31 | 3/2 | 0.283 | 0.1710 | 1.013E10 |
2-3 | 1/2 | 0.0365 | 0.0513 | 1.285E9 |
2-6 | 3/2 | 31.9E-6 | 2.93E-6 | 7.094E4 |
2-7 | 1/2 | 13.6E-5 | 7.75E-5 | 3.757E6 |
2-9 | 1/2 | 72.0E-3 | 3.62E-3 | 2.055E8 |
2-12 | 3/2 | 7.51E-3 | 3.96E-3 | 1.137E8 |
2-13 | 3/2 | 4.16E-4 | 3.95E-4 | 1.169E7 |
2-14 | 1/2 | 6.77E-4 | 7.17E-4 | 4.382E7 |
2-15 | 3/2 | 8.56E-3 | 3.31E-3 | 9.929E7 |
2-16 | 3/2 | 15.9E-5 | 6.84E-5 | 2.149E6 |
2-25 | 3/2 | 11.7E-3 | 7.62E-3 | 3.193E8 |
2-27 | 1/2 | 0.2115 | 0.4553 | 4.403E10 |
2-28 | 3/2 | 0.2402 | 0.1052 | 5.468E9 |
2-29 | 1/2 | 1.833 | 1.091 | 1.196E11 |
2-31 | 3/2 | 4.004 | 3.213 | 1.810E11 |
BD | Present | Measured | |
Lifetime ps. | 344 | 242 | ![]() |
Branch ratio | 2.17 | 2.22 | ![]() |
i-i' | 18.0 | 27.0 | 36.0 | 45.0 |
1-3 | .356 | .363 | .361 | .361 |
BD | .421 | .441 | .461 | .479 |
2-3 | .186 | .188 | .188 | .188 |
BD | .226 | .239 | .252 | .262 |
1-4 | .044 | .028 | .020 | .015 |
BD | .039 | .026 | .018 | .013 |
2-4 | .014 | .0085 | .0060 | .0045 |
BD | .012 | .0079 | .0056 | .0042 |
3-4 | .0020 | .0013 | .0010 | .0008 |
BD | .0020 | .0013 | .0009 | .0007 |
1-5 | .0662 | .0423 | .0293 | .0213 |
BD | .0593 | .0383 | .0265 | .0193 |
© ESO 2001