Upper | Lower | ![]() |
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BF | Aa | Unc. | |
level | level | (cm-1) | (Å) | Theoryb | Exp. | (107 s-1) | (%) |
4p(5D) 6F1/2 | 4s(5D) 6D1/2 | 34 861.58 | 2867.645 | 0.78 | 0.76 | 17.70 | 3 |
4s(5D) 6D3/2 | 34 790.81 | 2873.479 | 0.22 | 0.24 | 5.57 | 6 | |
Residual | 0.00 | ||||||
4p(5D) 6F3/2 | 4s(5D) 6D1/2 | 34 943.36 | 2860.934 | 0.31 | 0.30 | 7.24 | 5 |
4s(5D) 6D3/2 | 34 872.59 | 2866.740 | 0.57 | 0.57 | 13.60 | 3 | |
4s(5D) 6D5/2 | 34 757.35 | 2876.245 | 0.12 | 0.12 | 2.95 | 5 | |
Residual | 0.01 | ||||||
4p(5D) 6F5/2 | 4s(5D) 6D3/2 | 35 007.77 | 2855.670 | 0.47 | 0.47 | 11.30 | 4 |
4s(5D) 6D5/2 | 34 892.53 | 2865.102 | 0.47 | 0.46 | 11.10 | 4 | |
4s(5D) 6D7/2 | 34 736.49 | 2877.973 | 0.06 | 0.06 | 1.44 | 6 | |
Residual | 0.01 | ||||||
4p(5D) 6F7/2 | 4s(5D) 6D5/2 | 35 079.42 | 2849.837 | 0.63 | 0.62 | 15.20 | 3 |
4s(5D) 6D7/2 | 34 923.38 | 2862.571 | 0.35 | 0.36 | 8.66 | 5 | |
4s(5D) 6D9/2 | 34 730.80 | 2878.444 | 0.02 | 0.02 | 0.48 | 8 | |
Residual | 0.00 | ||||||
4p(5D) 6F9/2 | 4s(5D) 6D7/2 | 35 160.69 | 2843.249 | 0.81 | 0.80 | 18.90 | 3 |
4s(5D) 6D9/2 | 34 968.11 | 2858.909 | 0.19 | 0.20 | 4.87 | 6 | |
Residual | 0.00 | ||||||
4p(5D) 6F11/2 | 4s(5D) 6D9/2 | 35 255.18 | 2835.629 | 1.00 | 1.00 | 25.00 | 3 |
Residual | 0.00 | ||||||
4p(5D) 6D1/2 | 4s(5D) 6D1/2 | 37 530.96 | 2663.675 | 0.20 | 0.18 | 4.29 | 8 |
4s(5D) 6D3/2 | 37 460.19 | 2668.707 | 0.67 | 0.62 | 14.50 | 8 | |
4s(5D) 4D1/2 | 29 964.52 | 3336.321 | 0.06 | 0.09 | 2.02 | 14 | |
4s(5D) 4D3/2 | 29 861.60 | 3347.820 | 0.06 | 0.09 | 2.10 | 14 | |
Residual | 0.02 | ||||||
4p(5D) 6D3/2 | 4s(5D) 6D1/2 | 37 602.79 | 2658.586 | 0.33 | 0.26 | 6.24 | 8 |
4s(5D) 6D3/2 | 37 532.02 | 2663.599 | 0.01 | 0.02 | 0.56 | 9 | |
4s(5D) 6D5/2 | 37 416.78 | 2671.803 | 0.51 | 0.46 | 10.90 | 7 | |
4s(5D) 4D1/2 | 30 036.35 | 3328.342 | 0.01 | 0.01 | 0.30 | 22 | |
4s(5D) 4D3/2 | 29 933.43 | 3339.786 | 0.04 | 0.07 | 1.58 | 13 | |
4s(5D) 4D5/2 | 29 766.72 | 3358.491 | 0.09 | 0.13 | 3.17 | 13 | |
4s(5D) 4P1/2 | 27 740.76 | 3603.776 | 0.01 | 0.03 | 0.79 | 14 | |
Residual | 0.02 | ||||||
4p(5D) 6D5/2 | 4s(5D) 6D3/2 | 37 319.22 | 2678.789 | 0.31 | 0.36 | 8.02 | 7 |
4s(5D) 6D5/2 | 37 203.98 | 2687.087 | 0.12 | 0.19 | 4.29 | 7 | |
4s(5D) 6D7/2 | 37 047.94 | 2698.405 | 0.35 | 0.20 | 4.39 | 8 | |
4s(5D) 4D5/2 | 29 553.92 | 3382.675 | 0.03 | 0.05 | 1.02 | 9 | |
4s(5D) 4D7/2 | 29 327.79 | 3408.757 | 0.15 | 0.16 | 3.61 | 9 | |
3d5 4P5/2 | 27 529.28 | 3631.461 | 0.02 | 0.02 | 0.50 | 10 | |
3d5 4P3/2 | 27 527.69 | 3631.671 | 0.01 | 0.01 | 0.18 | 16 | |
Residual | 0.01 | ||||||
4p(5D) 6D7/2 |
4s(5D) 6D5/2 | 37 497.95 | 2666.020 | 0.35 | 0.35 | 9.19 | 23 |
4s(5D) 6D7/2 | 37 341.91 | 2677.161 | 0.45 | Blc | 11.90 | ||
4s(5D) 6D9/2 | 37 149.33 | 2691.040 | 0.20 | 0.19 | 5.13 | 23 | |
Residual | 0.46 | ||||||
4p(5D) 6D9/2 | 4s(5D) 6D7/2 | 37 534.52 | 2663.422 | 0.20 | 0.20 | 5.28 | 40 |
4s(5D) 6D9/2 | 37 341.94 | 2677.159 | 0.79 | Blc | 20.90 | ||
4s(5D) 4D7/2 | 29 814.37 | 3353.124 | 0.00 | 0.01 | 0.15 | 42 | |
Residual | 0.79 | ||||||
4p(5D) 6P3/2 | 3d5 6S5/2 | 48 398.95 | 2065.501 | 0.39 | 0.28 | 11.70 | 9 |
4s(5D) 6D1/2 | 36 437.14 | 2743.641 | 0.16 | 0.18 | 7.66 | 9 | |
4s(5D) 6D3/2 | 36 366.37 | 2748.980 | 0.25 | 0.28 | 11.60 | 9 | |
4s(5D) 6D5/2 | 36 251.13 | 2757.720 | 0.19 | 0.24 | 9.97 | 9 | |
4s(5D) 4D3/2 | 28 767.78 | 3475.116 | 0.00 | 0.01 | 0.33 | 20 | |
4s(5D) 4D5/2 | 28 601.07 | 3495.373 | 0.00 | 0.01 | 0.27 | 22 | |
Residual | 0.00 | ||||||
4p(5D) 6P5/2 | 3d5 6S5/2 | 48 491.10 | 2061.575 | 0.39 | 0.31 | 12.80 | 9 |
4s(5D) 6D3/2 | 36 458.52 | 2742.032 | 0.06 | 0.07 | 3.02 | 9 | |
4s(5D) 6D5/2 | 36 343.28 | 2750.727 | 0.21 | 0.23 | 9.56 | 9 | |
4s(5D) 6D7/2 | 36 187.24 | 2762.589 | 0.33 | 0.38 | 15.90 | 9 | |
4s(5D) 4D7/2 | 28 467.09 | 3511.824 | 0.00 | 0.01 | 0.31 | 17 | |
Residual | 0.00 | ||||||
4p(5D) 6P7/2 | 3d5 6S5/2 | 48 632.12 | 2055.596 | 0.40 | 0.31 | 12.90 | 9 |
4s(5D) 6D5/2 | 36 484.30 | 2740.094 | 0.02 | 0.02 | 0.89 | 12 | |
4s(5D) 6D7/2 | 36 328.26 | 2751.864 | 0.12 | 0.13 | 5.57 | 9 | |
4s(5D) 6D9/2 | 36 135.68 | 2766.531 | 0.47 | 0.54 | 22.30 | 9 | |
Residual | 0.00 | ||||||
4p(5D) 4F3/2 | 4s(5D) 4D1/2 | 32 055.90 | 3118.646 | 0.57 | 0.57 | 13.60 | 10 |
4s(5D) 4D3/2 | 31 952.98 | 3128.692 | 0.21 | 0.21 | 5.05 | 11 | |
3d5 4G5/2 | 31 072.09 | 3217.393 | 0.18 | 0.18 | 4.35 | 11 | |
Residual | 0.04 | ||||||
4p(5D) 4F5/2 | 4s(5D) 4D3/2 | 32 038.31 | 3120.359 | 0.61 | 0.60 | 14.60 | 10 |
4s(5D) 4D5/2 | 31 871.60 | 3136.681 | 0.18 | 0.18 | 4.36 | 11 | |
3d5 4G7/2 | 31 151.65 | 3209.176 | 0.16 | 0.17 | 4.19 | 11 | |
Residual | 1.00 | 0.05 | |||||
4p(5D) 4F7/2 | 4s(5D) 6D7/2 | 39 485.02 | 2531.845 | 0.00 | 0.01 | 0.24 | 12 |
4s(5D) 4D5/2 | 31 991.00 | 3124.973 | 0.69 | 0.68 | 16.50 | 8 | |
4s(5D) 4D7/2 | 31 764.87 | 3147.220 | 0.10 | 0.10 | 2.50 | 9 | |
3d5 4G9/2 | 31 269.55 | 3197.075 | 0.16 | 0.16 | 3.97 | 9 | |
4s(3F) 4F7/2 | 20 620.30 | 4848.235 | 0.01 | 0.01 | 0.36 | 18 | |
Residual | 0.04 | ||||||
4p(5D) 4F9/2 | 4s(5D) 6D9/2 | 39 446.26 | 2534.333 | 0.01 | 0.02 | 0.50 | 12 |
4s(5D) 4D7/2 | 31 918.69 | 3132.053 | 0.78 | 0.76 | 18.60 | 7 | |
3d5 4G11/2 | 31 430.60 | 3180.693 | 0.17 | 0.17 | 4.21 | 9 | |
3d5 4D7/2 | 26 909.00 | 3715.172 | 0.00 | 0.01 | 0.21 | 18 | |
4s(3F) 4F9/2 | 20 723.35 | 4824.127 | 0.01 | 0.01 | 0.35 | 16 | |
Residual | 0.03 | ||||||
4p(5D) 4D1/2 | 4s(5D) 4D1/2 | 34 889.77 | 2865.328 | 0.34 | 0.33 | 7.73 | 11 |
4s(5D) 4D3/2 | 34 786.85 | 2873.806 | 0.36 | 0.37 | 8.50 | 11 | |
3d5 4D1/2 | 29 382.62 | 3402.396 | 0.09 | 0.08 | 1.88 | 16 | |
3d5 4D3/2 | 29 375.21 | 3403.254 | 0.09 | 0.08 | 1.93 | 16 | |
3d5 4F3/2 | 21 573.26 | 4634.070 | 0.05 | 0.07 | 1.63 | 16 | |
Residual | 1.00 | 0.07 | |||||
4p(5D) 4D3/2 | 4s(5D) 4D1/2 | 34 971.27 | 2858.650 | 0.16 | 0.16 | 3.74 | 11 |
4s(5D) 4D3/2 | 34 868.35 | 2867.089 | 0.28 | 0.28 | 6.60 | 10 | |
4s(5D) 4D5/2 | 34 701.64 | 2880.863 | 0.26 | 0.27 | 6.37 | 10 | |
3d5 4D1/2 | 29 464.12 | 3392.985 | 0.05 | 0.04 | 0.96 | 11 | |
3d5 4D3/2 | 29 456.71 | 3393.838 | 0.07 | 0.06 | 1.49 | 10 | |
3d5 4D5/2 | 29 452.76 | 3394.293 | 0.07 | 0.07 | 1.53 | 10 | |
3d5 4F5/2 | 21 644.57 | 4618.803 | 0.04 | 0.03 | 0.79 | 12 | |
Residual | 0.09 | ||||||
4p(5D) 4D5/2 | 4s(5D) 4D3/2 | 34 994.45 | 2856.757 | 0.15 | 0.14 | 3.28 | 10 |
4s(5D) 4D5/2 | 34 827.74 | 2870.432 | 0.41 | 0.41 | 9.55 | 10 | |
4s(5D) 4D7/2 | 34 601.61 | 2889.192 | 0.15 | 0.16 | 3.70 | 10 | |
3d5 4P5/2 | 32 803.10 | 3047.606 | 0.02 | 0.05 | 1.24 | 12 | |
3d5 4P3/2 | 32 801.51 | 3047.754 | 0.02 | 0.01 | 0.32 | 21 | |
3d5 4D7/2 | 29 591.92 | 3378.331 | 0.04 | 0.04 | 0.85 | 12 | |
3d5 4D3/2 | 29 582.81 | 3379.371 | 0.05 | 0.04 | 0.97 | 11 | |
3d5 4D5/2 | 29 578.86 | 3379.822 | 0.10 | 0.09 | 1.99 | 11 | |
3d5 4F7/2 | 21 788.94 | 4588.199 | 0.04 | 0.03 | 0.79 | 12 | |
3d5 4F5/2 | 21 770.67 | 4592.049 | 0.01 | 0.01 | 0.20 | 37 | |
Residual | 0.02 | ||||||
4p(5D) 4D7/2 | 4s(5D) 4D5/2 | 34 986.60 | 2857.398 | 0.09 | 0.09 | 2.10 | 11 |
4s(5D) 4D7/2 | 34 760.47 | 2875.987 | 0.62 | 0.66 | 15.40 | 10 | |
3d5 4P5/2 | 32 961.96 | 3032.917 | 0.03 | 0.02 | 0.44 | 20 | |
3d5 4D7/2 | 29 750.78 | 3360.291 | 0.17 | 0.14 | 3.14 | 12 | |
3d5 4D5/2 | 29 737.72 | 3361.767 | 0.03 | 0.03 | 0.67 | 13 | |
3d5 4F9/2 | 21 930.17 | 4558.650 | 0.05 | 0.04 | 0.89 | 12 | |
Residual | 0.02 | ||||||
4p(5D) 4P1/2 | 4s(5D) 6D1/2 | 36 787.55 | 2717.506 | 0.06 | 0.08 | 1.68 | 8 |
4s(5D) 6D3/2 | 36 716.78 | 2722.744 | 0.19 | 0.31 | 6.13 | 6 | |
4s(5D) 4D1/2 | 29 221.11 | 3421.202 | 0.34 | 0.27 | 5.43 | 7 | |
4s(5D) 4D3/2 | 29 118.19 | 3433.295 | 0.33 | 0.26 | 5.28 | 7 | |
3d5 4P3/2 | 26 925.25 | 3712.930 | 0.06 | 0.06 | 1.13 | 9 | |
Residual | 0.02 | ||||||
4p(5D) 4P3/2 | 4s(5D) 6D1/2 | 37 044.12 | 2698.683 | 0.18 | 0.29 | 6.24 | 6 |
4s(5D) 6D3/2 | 36 973.35 | 2703.849 | 0.03 | 0.04 | 0.93 | 7 | |
4s(5D) 6D5/2 | 36 858.11 | 2712.303 | 0.10 | 0.17 | 3.61 | 6 | |
4s(5D) 4D1/2 | 29 477.68 | 3391.424 | 0.03 | 0.03 | 0.58 | 11 | |
4s(5D) 4D3/2 | 29 374.76 | 3403.307 | 0.20 | 0.15 | 3.12 | 7 | |
4s(5D) 4D5/2 | 29 208.05 | 3422.732 | 0.37 | 0.25 | 5.37 | 6 | |
3d5 4P5/2 | 27 183.41 | 3677.667 | 0.03 | 0.02 | 0.38 | 11 | |
3d5 4P1/2 | 27 182.09 | 3677.846 | 0.03 | 0.02 | 0.39 | 11 | |
3d5 4P3/2 | 27 181.82 | 3677.882 | 0.01 | 0.01 | 0.19 | 19 | |
Residual | 0.02 | ||||||
4p(5D) 4P5/2 | 4s(5D) 6D3/2 | 37 673.75 | 2653.578 | 0.20 | 0.18 | 3.81 | 6 |
4s(5D) 6D5/2 | 37 558.51 | 2661.721 | 0.12 | 0.05 | 1.14 | 6 | |
4s(5D) 6D7/2 | 37 402.47 | 2672.826 | 0.08 | 0.26 | 5.74 | 6 | |
4s(5D) 4D3/2 | 30 075.16 | 3324.047 | 0.01 | 0.01 | 0.30 | 14 | |
4s(5D) 4D5/2 | 29 908.45 | 3342.576 | 0.10 | 0.07 | 1.54 | 6 | |
4s(5D) 4D7/2 | 29 682.32 | 3368.041 | 0.40 | 0.31 | 6.70 | 5 | |
3d5 4P5/2 | 27 883.81 | 3585.287 | 0.05 | 0.08 | 1.72 | 6 | |
3d5 4P3/2 | 27 882.22 | 3585.492 | 0.02 | 0.02 | 0.36 | 10 | |
Residual | 0.02 |
a Transition probabilities derived from the experimental BFs and lifetimes presented in Table 2. b Theoretical BFs calculated with the Cowan code (Cowan 1981). c Severly blended line. ; |