Table 1:
Peaks present in the spectra before the HF treatment.
Peak position |
Vibration mode |
Carrier |
Interpretation |
(cm-1) |
|
|
|
794-780 |
Si-O-Si bending |
silicate |
phyllosilicate |
806-800 |
Si-O-Si bending |
siloxane |
remaining silicone oila |
840-837 |
Si-O stretching |
silicate |
olivinea |
890-880 |
" |
silicate |
olivinea |
955-950 |
Si-O stretching |
silicate |
pyroxenea |
990-970 |
" |
silicate |
olivinea |
1014-1010 |
" |
silicate |
pyroxenea |
1018 |
" |
silicate |
phyllosilicatea |
1070-1060 |
Si-O stretching |
silicate |
pyroxenea |
1095-1080 |
Si-O stretching |
siloxane |
remaining silicone oila |
1260 |
Si-O stretching |
siloxane |
remaining silicone oila |
1375 |
COO- sym stretch |
organic |
carbox. acid salts |
1415-1400 |
|
|
unknown |
1457-1450 |
CO3- |
carbonate ion |
carbonates |
1583 |
COO- antisym stretch |
organic |
carbox. acid salts |
1667-1660 |
H-O-H bending |
water |
phyllosilicate |
3000-2800 |
CH2; CH3 sym and asym stretch |
organic |
aliphatic hydrocarbonsa |
2963 |
Si-O stretching |
siloxane |
remaining silicone oila |
3600-3100 (centered at 3400) |
OH stretch |
water |
water in phyllosil., carbox. acids, alcohols |
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