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Table 1: Detected sources: references indicate origin of specified coordinates.
Source $\alpha_{2000} \; (\rm h\;m\;s)$ $\delta_{2000}
\;(\hbox{$^\circ$ }\;\hbox{$^\prime$ }\;\hbox{$^{\prime\prime}$ })$ Previous ID $^{{\rm a}}$ Reference $^{{\rm a}}$ Notes
RCrA 1 19 01 41.5 -36 58 29 IRS2, TS13.1 2  
RCrA 2 $^{{\rm b}}$ 19 01 41.5 -36 58 59   17  
RCrA 3 19 01 41.7 -36 59 54 H$\alpha$2 1  
RCrA 4 19 01 48.0 -36 57 19 IRS5, TS2.4 2  
RCrA 5 19 01 50.7 -36 58 07 HH 100-IR, IRS1, TS2.6 2  
RCrA 6 $^{{\rm b}}$ 19 01 50.9 -36 57 37   17 Very close to RCrA
RCrA 7 $^{{\rm b}}$ 19 01 52.4 -36 57 37   17 Very close to RCrA
$\rho $ Oph A 1 16 26 17.3 -24 23 49 SKS9, ISO-Oph 21 6  
$\rho $ Oph A 2 16 26 18.8 -24 24 21 SKS11, ISO-Oph 26 ??? 17 Uncertain ID
$\rho $ Oph A 3 16 26 21.5 -24 23 07 GSS30, GY6, SKS12, ISO-Oph 29 6  
$\rho $ Oph A 4 16 26 23.7 -24 24 40 GY21, SKS16, ISO-Oph 37 6 Falls on bad column
$\rho $ Oph E 1 16 27 21.6 -24 41 43 GY252, SKS36, IKT43, ISO-Oph 132 6  
$\rho $ Oph E 2 16 27 24.8 -24 41 02 ISO-Oph 137 6  
$\rho $ Oph E 3 16 27 26.9 -24 39 23 GY262, IKT53, ISO-Oph 140 6  
$\rho $ Oph E 4 $^{{\rm b}}$ 16 27 27.1 -24 41 31   17 Very faint
$\rho $ Oph E 5 16 27 27.2 -24 40 49 GY265, IKT54, ISO-Oph 141 6  
$\rho $ Oph E 6 16 27 28.2 -24 39 32 GY269, IKT57, ISO-Oph 143 6  
Ser A 1 18 29 56.6 +1 12 56 SVS4/2, GEL5 11 Very faint
Ser A 2 18 29 56.7 +1 12 35 SVS4/3 11 Very faint
Ser A 3 18 29 57.5 +1 12 57 SVS4/5 and 11 Unresolved double
      SVS4/6, GEL9    
Ser A 4 18 29 57.9 +1 12 25 SVS4/7 11 Very faint
Ser A 5 18 29 57.9 +1 12 34 SVS4/8 11  
Ser A 6 18 29 57.9 +1 12 43 SVS4/9 and 11 Unresolved double
      SVS4/10, GEL11    
Ser A 7 $^{{\rm c}}$ 18 30 00.1 +1 13 03 GCNM130 13 Off frame 7.0-9.3 $\mu $m
Ser B 1 18 29 52.9 +1 14 55 GCNM53 13  
Ser B 2 18 29 55.7 +1 14 31 CK9, GEL4, EC74, GCNM76 13  
Ser B 3 18 29 56.8 +1 14 46 SVS2, CK3, GEL6, EC82, GCNM87 13 Unresolved double
      and GEL8, EC86, GCNM93    
Ser B 4 $^{{\rm b}}$ 18 29 57.2 +1 13 28   17 Peak in nebulosity?
Ser B 5 18 29 57.6 +1 15 31 GCNM100 13  
Ser B 6 18 29 57.7 +1 14 05 SVS20, CK1, GEL10, EC90, GCNM98 13 Double Object
Ser B 7 $^{{\rm b}}$ 18 29 58.1 +1 13 24   17 Peak in nebulosity?
Ser B 8 18 29 58.2 +1 15 21 CK4, GEL12, EC97, GCNM106 13 Falls on bad column
Ser B 9 18 29 58.7 +1 14 26 EC103, GCNM112 13  
Ser B 10 18 29 59.2 +1 14 08 CK8, GEL13, EC105, GCNM119 13  
Ser B 11 $^{{\rm c}}$ 18 30 00.1 +1 13 03 GCNM130 13  
Ser B 12 18 30 00.5 +1 15 20 CK2, EC118, GCNM136 13 Peaks on bad column
Ser B 13 18 30 02.1 +1 13 59 CK7, EC125, GCNM154 13 Very faint
Cha I 1 11 09 23.3 -76 34 35 C1-6, ISO-ChaI 189, KG82 15 Bad column in CVF1
Cha I 2 11 09 29.2 -76 33 30 ISO-ChaI 192, KG87 15 Out of frame in CVF1
Cha I 3 11 09 42.6 -76 35 01 C1-25, ISO-ChaI 199, KG93 15  
Cha I 4 11 09 46.9 -76 34 49 C1-24, ISO-ChaI 204, KG97 15  
Cha I 5 11 09 54.1 -76 34 26 C1-5, ISO-ChaI 223, KG109 15  
Cha I 6 11 10 00.8 -76 34 59 WW Cha, C1-7, ISO-ChaI 231, KG116 15  
$^{{\rm a}}$
Names and references from: 1) Marraco & Rydgren (1981) (H$\alpha$); 2) Taylor & Storey (1984) (TS, IRS); 3) Grasdalen et al. (1973) (GSS); 4) Greene & Young (1992) (GY); 5) Strom et al. (1995) (SKS); 6) Bontemps et al. (2001) (ISO-Oph); 7) Imanishi et al. (2001) (IKT); 8) Strom et al. (1976) (SVS); 9) Churchwell & Koornneef (1986) (CK); 10) Gomez de Castro et al. (1988) (GEL); 11) Eiroa & Casali (1989) (SVS4/?); 12) Eiroa & Casali (1992) (EC); 13) Giovannetti et al. (1998) (GCNM); 14) Hyland et al. (1982) / Jones et al. (1985) (C1-?); 15) Persi et al. (2000) (ISO-ChaI); 16) Kenyon & Gómez (2001) (KG); 17) this paper.
$^{{\rm b}}$
See Sect. 3.1.1 for a discussion of the sources not previously identified.
$^{{\rm c}}$
These two sources from the two different Serpens fields were determined to be different images of the same source.


 

 
Table 2: Fitting results: errors are given in parentheses (i.e. 7.84(16) $\leftrightarrow $ 7.84$\pm $0.16); source names correspond to those in Table 1.
  $\mu $m $\mu $m     Equivalent Line Widths (nm) Source Cont.    
Source flux continuum $\tau_{{\rm Si}}$ $^{{\rm a}}$ $\tau_{11~ \mu {\rm m}}$ $\mu $m 6.8 $\mu $m 7.6 $\mu $m 13 $\mu $m 15.2 $\mu $m $\alpha$ $\alpha$ Group $^{{\rm b}}$ Notes
  (Jy) flux (Jy)     H2O   CH4?? H2O CO2        
RCrA 1 7.84(16) 7.79(16) -0.02(1) -0.06(1) 178(8) $^{{\rm c}}$ 17(1) $^{{\rm c}}$ 17(3) $^{{\rm c}}$ 247(25) 168(7) 0.56 0.58 b Strong 11 $\mu $m emission
2 0.95(2) 1.24(3) 0.72(3) -0.27(4) 203(8) 57(4) 17(3) 0(0) 83(4) -0.96 $^{{\rm f}}$ -1.35 $^{{\rm f}}$ a Silicate too wide at long
                          $\lambda$, probable 13 $\mu $m error
3 0.27(2) 0.28(2) 0.22(1) -0.16(2) 147(15) $^{{\rm c}}$ 14(3) $^{{\rm c}}$ 0(0) $^{{\rm c}}$ 718(76) 0(0) -1.11 -0.96 b $\tau_{{\rm Si}}$ probably too small,
                          possible absorption bands
                          at 13 $\mu $m, 14.25 $\mu $m
4 1.74(110) 2.28(144) 0.71(3) -0.07(1) 271(10) 81(6) 6(1) 586(59) 253(11) 1.23 1.43 a Possible 10.5 $\mu $m emission
5 22.46(44) 36.91(74) 1.35(5) -0.23(3) 206(8) 67(4) 14(2) 1535(155) 129(5) 1.30 1.79 a  
6 0.94(3) 1.36(4) 0.95(4) -0.15(2) 204(7) 61(4) 11(2) 73(7) 97(4) -0.40 $^{{\rm f}}$ -0.42 $^{{\rm f}}$ a Under-estimates 13 $\mu $m
7 1.20(27) 1.62(37) 0.74(3) -0.08(1) 191(9) 86(6) 18(3) 0(0) 95(4) -0.18 $^{{\rm f}}$ -0.37 $^{{\rm f}}$ a Possible 10.5 $\mu $m emission,
                          under-estimates 13 $\mu $m
$\rho $ Oph A 1 0.42(2) 0.85(4) 2.11(11) -0.27(4) 27(3) 72(7) 19(3) 927(94) 57(3) -0.70 -0.20 a Poor 5-8 $\mu $m fit
2 0.21(2) 0.54(6) 2.68(19) -0.70(10) 207(14) 253(53) 79(9) 2611(319) 0(0) 0.34 1.36 a Definite 14 $\mu $m band
3 6.03(7) 8.99(10) 1.05(4) -0.20(3) 107(6) $^{{\rm c}}$ 0(0) $^{{\rm c}}$?? 0(0) $^{{\rm c}}$ 10(3) 87(3) 1.61 1.84 a Possible 7.1 $\mu $m band
4 $^{{\rm e}}$ 2.33(3) 2.74(4) 0.49(2) -0.16(2) 0(0) 25(12) 27(4) 687(69) 23(1) 0.95 1.15 b Silicate fit too wide
$\rho $ Oph E 1 2.88(3) 3.36(4) 0.52(2) -0.21(3) 140(5) 60(4) 27(4) 1206(121) 98(4) 0.15 0.43 b Silicate too wide
2 0.23(2) 0.56(5) 2.55(12) -0.36(5) 255(16) 93(7) 53(8) 1881(196) 324(20) -0.26 $^{{\rm f}}$ 0.51 $^{{\rm f}}$ a Deep 7.6 $\mu $m band
3 0.34(38) 0.65(72) 1.84(12) -0.27(4) 131(10) 134(13) 15(2) 1536(160) 155(7) -0.06 0.47 a Very deep 6.8 $\mu $m band
4 0.10(2) 0.17(4) 1.42(8) -0.23(4) 291(41) $^{{\rm c}}$ 0(0) $^{{\rm c}}$ 29(5) $^{{\rm c}}$ 1561(279) 501(49) -0.55 $^{{\rm f}}$ -0.01 $^{{\rm f}}$ a Very noisy: probably only
                          class, CO2, $\tau_{{\rm Si}}$ good data
5 2.62(4) 5.89(9) 2.22(8) -0.29(4) 218(14) 105(7) 20(3) 339(34) 207(8) 1.17 1.59 a  
6 4.60(25) 16.10(89) 3.31(13) -0.52(7) 306(12) 117(7) 0(0) 193(20) 112(4) 1.54 2.17 a  
Ser A 1 0.06(1) 0.15(3) 2.14(31) -0.60(9) 845(849) $^{{\rm c}}$ 356(161) $^{{\rm c}}$ 0(0) $^{{\rm c}}$ 2386(311) 298(33)? -0.24 0.47 a Noisy and faint, possible
                          12, 14 $\mu $m bands
2 0.06(1) 0.17(3) 2.39(61) -0.76(10) 965(878) $^{{\rm c}}$ 298(130) $^{{\rm c}}$ 0(0) $^{{\rm c}}$ 2679(437) 0(0) 0.43 1.35 a Noisy, possible absorption
                          bands at 11-16 $\mu $m
3 0.64(2) 1.24(4) 1.70(7) -0.32(4) 523(20) 165(11) 19(3) 1633(163) 285(13) 1.35 1.91 a Possible narrow absorption
                          band at 9.7 $\mu $m - CH3OH?
4 0.07(1) 0.15(2) 2.14(34) -0.46(7) 847(688) $^{{\rm c}}$ 271(69) $^{{\rm c}}$ 0(0) $^{{\rm c}}$ 2426(552) 269(51)? 0.42 1.17 a Noisy, possible absorption
                          bands at 11-16 $\mu $m
5 0.17(1) 0.30(2) 1.42(12) -0.37(5) 435(26) 165(11) 8(1) 1538(177) 186(11) 0.25 0.71 a Possible 12, 14 $\mu $m bands
6 0.46(1) 0.45(1) -0.18(1) -0.22(3) 272(17) 97(6) 0(0) 803(80) 223(9) 0.44 0.50 b Strong 11 $\mu $m emission
7 - - - - 954(312) $^{{\rm d}}$ - - - 504(59) - - a  


$^{{\rm a}}$ Values of $\tau_{{\rm Si}}$ between -0.8 and 0.6 are considered to be questionable, due to the presence of significant silicate emission and absorption (see discussion in Sect. 3.2.5).

$^{{\rm b}}$ Classification scheme proposed in Sect. 3.2.5.
$^{{\rm c}}$ Short wavelength features fitted using linear continuum, fitted from 5.6-7.9 $\mu $m, in cases where the automatic fitting procedure produced errors (see Sect. 2.5).
$^{{\rm d}}$ Feature fitted manually as spectrum was incomplete.
$^{{\rm e}}$ Source fell on bad column on array: data from these sources is not considered to be especially accurate.
$^{{\rm f}}$ No K-band data: $\alpha$ evaluated using $\lambda_1=8.0$ $\mu $m.



 
Table 2: continued.
  $\mu $m $\mu $m     Equivalent Line Widths (nm) Source Cont.    
Source flux continuum $\tau_{{\rm Si}}$ $^{{\rm a}}$ $\tau_{11~ \mu {\rm m}}$ $\mu $m 6.8 $\mu $m 7.6 $\mu $m 13 $\mu $m 15.2 $\mu $m $\alpha$ $\alpha$ Group $^{{\rm b}}$ Notes
  (Jy) flux (Jy)     H2O   CH4?? H2O CO2        
Ser B 1 0.19(1) 0.57(3) 2.76(16) -0.39(5) 703(44) 215(31) 0(0) 962(99) 267(14) 2.02 2.63 a Very deep absorption features
2 0.19(1) 0.16(1) -0.41(2) -0.23(3) 91(5) $^{{\rm c}}$ 39(3) $^{{\rm c}}$ 25(4) $^{{\rm c}}$ 0(0) 67(10) 0.14 0.04 b Large discontinuity at join,
                          poor fit from 8-12 $\mu $m
3 1.37(2) 0.77(2) -1.51(5) -0.10(1) 208(16) $^{{\rm c}}$ 33(2) $^{{\rm c}}$ 43(6) $^{{\rm c}}$ 1198(121) 202(8) 1.14 1.05 c Strong silicate emission,
                          fit too narrow
4 0.33(1) 0.28(1) -0.37(1) -0.19(3) 154(9) $^{{\rm c}}$ 45(4) $^{{\rm c}}$ 32(5) $^{{\rm c}}$ 0(0) 102(5) -1.03 $^{{\rm f}}$ -1.14 $^{{\rm f}}$ b Poss. 13 $\mu $m absorption band
5 0.10(1) 0.08(1) -0.57(3) -0.22(3) 208(8) 57(4) 29(4) 0(0) 59(4) 0.06 -0.09 b Long $\lambda$ fit probably wrong
6 6.16(14) 5.31(13) -0.33(1) -0.12(2) 137(5) $^{{\rm c}}$ 38(2) $^{{\rm c}}$ 24(4) $^{{\rm c}}$ 0(0) 103(4) -0.11 -0.18 b Poor 8-11 $\mu $m fit
7 0.35(1) 0.32(1) -0.14(1) -0.15(2) 152(7) $^{{\rm c}}$ 50(4) $^{{\rm c}}$ 23(3) $^{{\rm c}}$ 0(0) 100(4) -1.13 $^{{\rm f}}$ -1.10 $^{{\rm f}}$ b Large discontinuity at join
8 $^{{\rm e}}$ 0.31(1) 0.27(1) -0.36(1) -0.11(1) 62(4) 0(0) 1(1) 554(56) 27(3) -0.31 -0.29 b  
9 0.35(1) 0.53(2) 1.02(4) -0.20(3) 237(8) 38(4) 25(4) 1119(114) 144(6) 0.99 1.33 a Dubious 6.8 $\mu $m and 7.5 $\mu $m fits
10 0.36(1) 0.33(1) 0.04(1) -0.06(1) 168(11) $^{{\rm c}}$ 35(3) $^{{\rm c}}$ 23(3) $^{{\rm c}}$ 609(61) 126(6) -0.43 -0.34 b Probably peak in nebulosity
11 0.36(2) 1.89(10) 4.34(31) -0.62(8) 984(45) 350(67) 73(11) 1996(202) 479(28) 2.07 3.14 a Very deep absorption features
12 $^{{\rm e}}$ - - - - 414(76) $^{{\rm c}}$? 0(0) $^{{\rm c}}$? 19(5) $^{{\rm c}}$? - 143(16)? - - - Very dubious measurements:
                          peaks on bad column
13 0.04(1) 0.07(2) 1.35(22) -0.20(3) 348(51) $^{{\rm c}}$ 146(46) $^{{\rm c}}$ 69(11) $^{{\rm c}}$ 2496(291) 185(7) 0.55 1.09 a Good fit but very faint
Cha I 1 $^{{\rm e}}$ 0.71(2) 0.65(2) -0.18(1) -0.07(1) 0(0) 0(0) 7(1) 548(55) 0(0) -0.32 -0.28 b Poor fit, due to large
                          discontinuity at join
2 - - - - - - - - 150(6) 1.81 - a  
3 0.14(1) 0.13(1) -0.37(2) -0.07(1) 144(10) $^{{\rm c}}$ 36(3) $^{{\rm c}}$ 10(2) $^{{\rm c}}$ 0(0) 0(0) -0.40 -0.52 b Noisy, poor fit at long $\lambda$
4 0.04(1) 0.02(1) -1.88(11) 0.13(2) 225(25) $^{{\rm c}}$ 87(9) $^{{\rm c}}$ 0(0) $^{{\rm c}}$ 0(0) 0(0) -0.65 -1.09 c Very faint, low S/N
5 3.58(6) 3.59(6) 0.00(1) -0.12(2) 41(2) $^{{\rm c}}$ 0(0) $^{{\rm c}}$ 7(1) $^{{\rm c}}$ 283(28) 0(0) -0.43 -0.37 b Strong 11 $\mu $m emission
6 3.18(6) 1.93(4) -1.32(5) -0.04(1) 0(0) 0(0) 0(0) 0(0) 0(0) -0.85 -1.07 c Silicate fit too narrow


$^{{\rm a}}$] Values of $\tau_{{\rm Si}}$ between -0.8 and 0.6 are considered to be questionable, due to the presence of significant silicate emission and absorption (see discussion in Sect. 3.2.5).

$^{{\rm b}}$] Classification scheme proposed in Sect. 3.2.5.
$^{{\rm c}}$] Short wavelength features fitted using linear continuum, fitted from 5.6-7.9 $\mu $m, in cases where the automatic fitting procedure produced errors (see Sect. 2.5).
$^{{\rm d}}$] Feature fitted manually as spectrum was incomplete.
$^{{\rm e}}$] Source fell on bad column on array: data from these sources is not considered to be especially accurate.
$^{{\rm f}}$] No K-band data: $\alpha$ evaluated using $\lambda_1=8.0$ $\mu $m.



 \begin{figure}\par\resizebox{16cm}{!}{
\begin{turn}{270}
\includegraphics{3047...
...\par \begin{turn}{270}
\includegraphics{3047_fa1.6}
\end{turn} }
\end{figure} Figure A.1: Spectra of RCrA 1-6.


 \begin{figure}\par\resizebox{16cm}{!}{
\begin{turn}{270}
\includegraphics{3047...
...\par \begin{turn}{270}
\includegraphics{3047_fa2.6}
\end{turn} }
\end{figure} Figure A.2: Spectra of RCrA 7, $\rho $ Oph A 1-4 and $\rho $ Oph E 1. Note that source $\rho $ Oph A 4 fell on the bad column on the array.


 \begin{figure}\par\resizebox{16cm}{!}{
\begin{turn}{270}
\includegraphics{3047...
...\par \begin{turn}{270}
\includegraphics{3047_fa3.6}
\end{turn} }
\end{figure} Figure A.3: Spectra of $\rho $ Oph E 2-6 and Ser A 1.


 \begin{figure}\par\resizebox{16cm}{!}{
\begin{turn}{270}
\includegraphics{3047...
...\par \begin{turn}{270}
\includegraphics{3047_fa4.6}
\end{turn} }
\end{figure} Figure A.4: Spectra of Ser A 2-6 and Ser B 1. The partial spectrum of Ser A 7 is omitted as a complete spectrum of the same object was found as Ser B 11. Note also that both Ser A 3 and 6 were found to be unresolved doubles.


 \begin{figure}\par\resizebox{16cm}{!}{
\begin{turn}{270}
\includegraphics{3047...
...\par \begin{turn}{270}
\includegraphics{3047_fa5.6}
\end{turn} }
\end{figure} Figure A.5: Spectra of Ser B 2-7. Note that Ser B 3 and 6 are both unresolved doubles.


 \begin{figure}\par\resizebox{16cm}{!}{
\begin{turn}{270}
\includegraphics{3047...
...\par \begin{turn}{270}
\includegraphics{3047_fa6.6}
\end{turn} }
\end{figure} Figure A.6: Spectra of Ser B 8-13. Source Ser B 8 fell on the bad column of the array, so the data are somewhat dubious. Ser B 12 peaked on the bad column and the resulting spectrum is very poor, so no fit was possible.


 \begin{figure}\par\resizebox{16cm}{!}{
\begin{turn}{270}
\includegraphics{3047...
...\par \begin{turn}{270}
\includegraphics{3047_fa7.6}
\end{turn} }
\end{figure} Figure A.7: Spectra of Cha I 1-6. Cha I 1 fell on the bad column in CVF1, resulting in the large discontinuity seen at the join. Due to the rotation of the spacecraft Cha I 2 was only observed in CVF2.


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