Table A.1
Experimental spectroscopic parameters for the A-symmetry substate of trans-MF (A-Reduction, Ir-Representation).
Parameters | trans-MF |
---|---|
A(a) (MHz) | 62897.147 ± 0.004(e) |
B (MHz) | 4725.7172 ± 0.0004 |
C (MHz) | 4398.5091 ± 0.0004 |
|μa|/|μb|/|μ|(b)(D) | 4.2/2.5/0.0 |
ΔJ (kHz) | 1.151 ± 0.009 |
ΔJK (kHz) | −74.6 ± 0.2 |
δJ (kHz) | 0.1100 ± 0.0005 |
N. A lines | 24 |
σ(c)(kHz) | 20 |
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0.59 |
Notes. (a) A, B, and C represent the rotational constants (in MHz). (b)|µa|, |µb|, |µc| are the absolute values of the electric dipole moment components (in D), obtained theoretically in Neill et al. (2012). (c) Root mean square (RMS) deviation of the fit. (d) Dimensionless rms, defined as , where the δ’s are the residuals weighted by the experimental uncertainty and NA the total number of measured transitions analyzed belonging to the A-symmetry substate.
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