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Fig. A.1

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Model spectrum, in colour, over the observed data, in black, of AFGL 2591 for transition lines of (a) CH3CCH on the brightest pixel of the CH3CCH 50−40 (Eup = 12 K), line, and (b) c-C3H2 on the brightest pixel of the c-C3H2 21,2−10,1 (Eup = 6 K), line. One component is used to fit the two carbon chain molecules together. The dashed grey line represents the observed transition frequency, with the energy level of this transition labelled.

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