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Table A.1

Atomic constants for CoI and CuI used to compute hyperfine structure: A and B constants from Pickering (1996) for CoI. For CuI,the A and B constants are from Kurúcz (1993) and Biehl (1976), and they are reported in Ernandes et al. (2018).

Species λ (Å) Lower level J A(mK) A(MHz) B(mK) B(MHz) Upper level J A(mK) A(MHz) B(mK) B(MHz)
59CoI 4749.612 (4F)4sp z6D 9/2 28.05 840.9180 0.08 2.3983 (5F)s5s e6F 11/2 31.45 942.8475 0.07 2.0985
                             
59CoI 5212.691 (4F)4sp z4F 9/2 27.02 810.0394 0.08 2.3983 (5F)s5s f4F 11/2 35.92 1076.8546 0.07 2.0985
                             
59CoI 5280.629 (4F)4sp z4G 9/2 17.25 517.1420 0.09 2.6981 (5F)s5s f4F 7/2 28.25 846.9138 0.07 2.0985
                             
59CoI 5301.047 d7s4 a44P 5/2 5.90 176.8776 0.20 5.9959 (3F)4p y4D 5/2 15.50 464.6784 0.20 5.9959
                             
59CoI 5342.708 (3F)4p y4G 11/2 10.0 299.7925 0.20 5.9959 (3F)4d e4H 13/2 7.60 227.8423 0.20 5.9959
                             
59CoI 5454.572 (3F)4p y4F 9/2 9.90 296.7946 0.10 2.9979 (3F)4d g4F 9/2 9.18 275.2095 0.08 2.3983
                             
59CoI 5647.234 (3P)4s a2P 3/2 11.20 335.7676 0.20 5.9959 (3F)4p y3D 5/2 16.40 491.6597 0.10 2.9979
                             
59CoI 6117.000 d4s2 a4P 1/2 −23.60 -707.5103 0.20 5.9959 3(4F)4sp z4D 1/2 27.50 824.4294 0.10 2.9979
                             
59CoI 6188.996 d7s2 a4P 5/2 5.90 176.8776 0.08 2.3983 (5F)4sp z4D 5/2 23.22 696.1182 0.09 2.6981

63CuI 5105.537 4p 2P [case e] 1.5 6.5 194.865 −0.96 −28.78 4s2 2D [case b] 2.5 24.97 748.582 6.20 185.871
                             
5218.197 4p 2P [case e] 1.5 6.5 194.865 −0.96 −28.78 4d 2D [—] 2.5 0.0* 0.0* 0.0* 0.0*

65CuI 5105.537 4p 2P [case e] 1.5 6.96 208.66 −0.86 −25.78 4s2 2D [case b] 2.5 26.79 803.14 5.81 174.18
                             
5218.197 4p 2P [case e] 1.5 6.96 208.66 −0.86 −25.78 4d 2D [—] 2.5 0.0* 0.0* 0.0* 0.0*

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