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Table A.1

Atomic constants for ScI and ScII used to compute hyperfine structure.


Species λ (Å) Lower level J A(mK) A(MHz) B(mK) B(MHz) Upper level J A(mK) A(MHz) B(mK) B(MHz)
45ScI 5671.805 3d2(3F)4s 4F 9/2 +9.5 284.8029 –0.4 –11.9917 3d2(3F)4p 4G 11/2 +1.5 44.9689
45ScI 5686.826 3d2(3F)4s 4F 7/2 +8.3 248.8278 –0.3 –8.9938 3d2(3F)4p 4G 7/2 +4.9 146.8983
45ScI 6210.676 3d4s2 2D 3/2 +8.98 269.2137 –0.88 –26.3817 3d4s(1D)4p 2D 3/2 –11.5 –344.7614

45ScII 5526.790 3p63d2 1G 4.0 M 135.232 M –63.44 3p63d4p 1Fo 3.0 193.1 –65
45ScII 5552.224 3p64s2 1S 0.0 3p63d4p 3Po 1.0 258.0 12.0
45ScII 5657.896 3p63d2 3P 2.0 M -27.732 M 22.13 3p63d4p 3Po 2.0 105.6 –21
45ScII 5684.202 3p63d2 3P 2.0 –27.2 26.0 3p63d4p 3Po 1.0 258.0 12.0
45ScII 6245.637 3p63d2 3P 2.0 M –27.732 22.13 3p63d4p 3Do 3.0 101.8 24
45ScII 6300.698 3p63d2 3P 2.0 –27.2 26.0 3p63d4p 3Do 2.0 125.7 6.0
45ScII 6320.84 3p63d2 3P 1.0 –108.1 –13.0 3p63d4p 3Do 1.0 307.0 1.0
45ScII 6604.601 3p63d2 1D 2.0 149.361 7.818 3p63d4p 1Do 2.0 215.7 18

51VI 5703.560 3d4(5)D)4s a4D 3/2 7.5581 2.0751 3d4(5)D)4p y4F 5/2 216.05 0.05
51VI 6081.440 3d4(5)D)4s a4D 3/2 7.5581 2.0751 3d4(5)D)4p z4P 3/2 –286.42 –6.02
51VI 6090.220 3d4(5)D)4s a4D 7/2 –160.1721 15.2561 3d4(5)D)4p z4P? 5/2 –89.82 8.02
51VI 6119.520 3d4(5)D)4s a4D 5/2 –143.3671 1.0671 3d4(5)D)4p z4P 3/2 –286.42 –6.02
51VI 6199.190 3d4(5)D)4s a6D 7/2 382.3681 2.2201 3d3(4F)4s4p(3P0) z6D 9/2 503.464 3.34
51VI 6243.100 3d4(5)D)4s a6D 9/2 406.8541 14.7211 3d3(4F)4s4p(3P0) z6D 9/2 503.464 3.34
51VI 6251.820 3d4(5)D)4s a6D 7/2 382.3681 2.2201 3d3(4F)4s4p(3P0) z6D 7/2 514.354 –1.24
51VI 6274.650 3d4(5)D)4s a6D 3/2 405.6051 –8.0601 3d3(4F)4s4p(3P0) z6D 1/2 939.944 0.04
51VI 6285.160 3d4(5)D)4s a6D 5/2 373.5951 –2.5751 3d3(4F)4s4p(3P0) z6D 3/2 594.694 –4.44

63CuI 5105.537 4p 2P [case e] 1.5 6.5 194.865 –0.96 –28.78 4s2 2D [case b] 2.5 24.97 748.582 6.20 185.871
5218.197 4p 2P [case e] 1.5 6.5 194.865 –0.96 –28.78 4d 2D [–] 2.5 0.0* 0.0* 0.0* 0.0*

65CuI 5105.537 4p 2P [case e] 1.5 6.96 208.66 –0.86 –25.78 4s2 2D [case b] 2.5 26.79 803.14 5.81 174.18
5218.197 4p 2P [case e] 1.5 6.96 208.66 –0.86 –25.78 4d 2D [–] 2.5 0.0* 0.0* 0.0* 0.0*

Notes. A and B constants from Mansour et al. (1989), Villemoes et al. (1992) for ScII and Biehl (1976) for ScI. For VI the A and B constants are from 1 UBDE, Unkel et al. (1989). 2 CPGC, Childs et al. (1979). 3 PBAG, Palmeri et al. (1995). 4 CBFG, Cochrane et al. (1998). 5 LGB, Lefèbvre et al. (2002). B constants not available in the literature are assumed as null.

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