\begin{table}%t2 \caption{\label{ACbands}Infrared absorption bands and assignments of the products formed from a binary NH$_{3}$:CO$_{2}$=1:1.} \par %\centerline { \begin{tabular}{lcc} \hline\hline \multicolumn{1}{c}{Assignment}&\multicolumn{1}{c}{Wavenumbers }&\multicolumn{1}{c}{Band Strength}\\ \multicolumn{1}{c}{}&\multicolumn{1}{c}{(cm$^{-1}$)}&\multicolumn{1}{c}{(cm~molecule$^{-1}$)}\\\hline $\nu$~(NH$_{2}$) NH$_{2}$COOH dimer & 3462 & \\ $\nu$~(NH$_{2}$) [NH$_{2}$COO$^{-}$][NH$_{4}$$^{+}$] & \\ $\nu$~(NH$_{2}$) [NH$_{2}$COO$^{-}$][NH$_{4}$$^{+}$] & 3325& \\ $\nu$~(OH) NH$_{2}$COOH dimer& (broad) 3140 & \\ $\nu$~(C=O) NH$_{2}$COOH dimer& 1691& $5\times10^{-18}$ \\ $\delta$~(NH$_{2}$) [NH$_{2}$COO$^{-}$][NH$_{4}$$^{+}$]& 1623 & $2\times10^{-18}$\\ $\nu_{\rm as}$~(COO$^{-}$) [NH$_{2}$COO$^{-}$][NH$_{4}$$^{+}$] & 1553 & $2\times10^{-17}$\\ $\delta$~(NH$_{4}$$^{+}$) [NH$_{2}$COO$^{-}$][NH$_{4}$$^{+}$] & 1495 & $3\times10^{-18}$ \\ NH$_{2}$COOH dimer& 1451 & $2\times10^{-18}$\\ $\nu_{\rm s}$~(COO$^{-}$) [NH$_{2}$COO$^{-}$][NH$_{4}$$^{+}$] & 1393 & $8\times10^{-18}$\\ NH$_{2}$COOH dimer& 1320 &$2\times10^{-18}$ \\ $\nu$~(CN) [NH$_{2}$COO$^{-}$][NH$_{4}$$^{+}$]& 1117 & $4\times10^{-18}$\\ $\rho$~(NH$_{2}$) [NH$_{2}$COO$^{-}$][NH$_{4}$$^{+}$] & 1037 & $2\times10^{-19}$\\ $\delta_{\rm oop}$~(OCN) [NH$_{2}$COO$^{-}$][NH$_{4}$$^{+}$] & 829 & $6\times10^{-19}$\\ $\delta$~(COO$^{-}$) [NH$_{2}$COO$^{-}$][NH$_{4}^{+}$] & 674 & $4\times10^{-19}$\\ \hline \end{tabular}} \medskip \par Vibration mode: stretching ($\nu$), bending ($\delta$), rocking ($\rho$), torsion ($\tau$).\\ Indication: asymmetric (as), symmetric (s) and out-of-plane (oop). \end{table}