\begin{table}%t1 \caption{\label{table1}Infrared absorption bands and assignments of NH$_{3}$ and CO$_{2}$, in pure solids and in NH$_{3}$:CO$_{2}$ ice mixtures at 10 K.} \par %\centerline { \begin{tabular}{lccc} \hline\hline\\[-3.5mm] \multicolumn{1}{c}{Assignment}&\multicolumn{2}{c}{Wavenumbers (cm$^{-1}$)}\\\hline NH$_{3}$ \cite{Ferraro80} & Solid & 1:1 ratio \\ $\nu_3$ & 3375 &3410; 3379 \\ $2\nu_4$ & 3290 & 3309 \\ $\nu_1$ & 3210 & 3219 \\ $\nu_4$ & 1625 & 1626\\ $\nu_2$ & 1075 &1064\\ $\nu_5$ & 530 & \\\hline CO$_{2}$ \cite{Gerakines95}& Solid & 1:1 ratio\\ $(\nu_1+\nu_3)$ & 3708 &3700 \\ $(2\nu_2+\nu_3)$ & 3600 &3594 \\ $(\nu_3)$ $\nu_{\rm as}$~CO$_{2}$ & 2337 &2333 \\ $(\nu_3)$ $\nu_{\rm as}$~$^{13}$CO$_{2}$ & 2282 & 2278 \\ $(\nu_2)$ $\delta$~CO$_{2}$ & 654 & 658 \\ \hline \end{tabular}} \medskip \par Vibration mode: stretching ($\nu$), bending ($\delta$).\\ Indication: asymmetric (as), symmetric (s). \end{table}