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Figure 1:
Partial energy level diagram of Sc II, showing the three lowest configurations. The lines measured in the present paper are 3d4s a
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Figure 2: Energy level diagram showing the pumping channels and major fluorescence decay used in the present experiment, with their approximate wavelengths. The laser is tuned to match the transitions to z3D or z3P, and the subsequent decay to a3D is observed. The level energies are not to scale. |
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Figure 3:
Decay curve for the a
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Figure 4:
Stern-Vollmer plot for the a
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Figure 5: Comparisons of experimental and theoretical lifetimes for the 3d2 a3P levels from the present work, and to previous calculations by Warner & Kirkpatrick (1969). |
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Figure 6: Spectrum showing the [Sc II] lines used in the present analysis. The upper level of each group is indicated. The transitions are listed in Table 3. |
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Figure 7: Branching fractions (BF) for 3d4s a3D-3d2 a3P. The experimental BFs are derived from the nebular spectrum, using the theoretical values for the residual lines. The 8328 Å line from a3P0 is not included since this is the only decay observed from this level, and thus makes the experimental BF uninteresting. |
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Figure 8: Transition rates (A-values) for the 3d4s a3D-3d2 a3P transitions. The difference between the theoretical and expermental values, compared to Fig. 4, is due to the difference in lifetimes between experiment and calculations. |
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