Upper levela | J | Lower levela | J | ![]() |
Experimentc | This work | |||||
Energy (cm-1) | Energy (cm-1) | BF | gA | BFd | gAe | log gfe | CFh | ||||
39 389.49 | 7/2 | 0.00 | 9/2 | 253.7986 | 0.914 | 107.5 | 0.307 | 37.2 | -1.44 | -0.030 | |
![]() |
3593.15 | 7/2 | 279.2758 | 0.012 | 1.4 | -2.79 | 0.004 | ||||
3928.94 | 5/2 | 281.9205 | 0.003 | 0.4 | 0.025 | 3.0 | -2.45 | -0.015 | |||
7891.93 | 5/2 | 317.3931 | 0.006 | 0.7 | 0.275 | 33.3 | -1.30 | 0.128 | |||
11 654.08 | 5/2 | 360.4471 | 0.198 | 24.0 | -1.33 | 0.185 | |||||
13 203.88 | 7/2 | 381.7808 | 0.002 | 0.2 | -3.36 | -0.024 | |||||
13 414.80 | 5/2 | 384.8810 | 0.024 | 2.8 | 0.171 | 20.7 | -1.34 | -0.127 | |||
41 282.95 | 9/2 | 0.00 | 9/2 | 242.1572 | 0.855 | 70.1 | -1.21 | -0.211 | |||
[![]() |
3593.15 | 7/2 | 265.2448 | 0.004 | 0.3 | -3.50 | -0.003 | ||||
11 459.90 | 7/2 | 335.2148 | 0.057 | 4.7 | -2.10 | 0.114 | |||||
13 203.88 | 7/2 | 356.0355 | 0.044 | 3.6 | -2.16 | -0.179 | |||||
17 242.26 | 7/2 | 415.8442 | 0.010 | 0.8 | -2.68 | 0.084 | |||||
43 802.36 | 7/2 | 0.00 | 9/2 | 228.2278 | 0.687 | 930.9 | 0.760 | 1147.2 | -0.05 | 0.331 | |
![]() |
3593.15 | 7/2 | 248.6242 | 0.230 | 311.5 | 0.155 | 226.4 | -0.68 | 0.097 | ||
3928.94 | 5/2 | 250.7181 | 0.015 | 20.4 | 0.016 | 24.1 | -1.64 | -0.020 | |||
7891.93 | 5/2 | 278.3885 | 0.026 | 35.1 | 0.010 | 15.1 | -1.76 | -0.018 | |||
11 459.90 | 7/2 | 309.1013 | 0.004 | 6.3 | -2.04 | -0.007 | |||||
11 654.08 | 5/2 | 310.9684 | 0.014 | 21.1 | -1.51 | -0.103 | |||||
13 203.88 | 7/2 | 326.7194 | 0.027 | 40.7 | -1.19 | 0.120 | |||||
13 414.80 | 5/2 | 328.9873 | 0.008 | 12.1 | -1.71 | 0.033 | |||||
15 605.58 | 9/2 | 354.5491 | 0.001 | 1.5 | -2.55 | 0.005 | |||||
17 242.26 | 7/2 | 376.3976 | 0.001 | 1.5 | -2.50 | -0.017 | |||||
21 590.81 | 9/2 | 450.0899 | 0.001 | 1.5 | -2.34 | -0.012 | |||||
44 315.40 | 9/2 | 0.00 | 9/2 | 225.5853 | 0.882 | 1729.4 | 0.12 | 0.454 | |||
![]() |
3593.15 | 7/2 | 245.4917 | 0.011 | 21.6 | -1.71 | 0.012 | ||||
11 459.90 | 7/2 | 304.2745 | 0.038 | 74.5 | -0.98 | -0.118 | |||||
13 203.88 | 7/2 | 321.3315 | 0.031 | 60.8 | -1.03 | 0.199 | |||||
17 242.26 | 7/2 | 369.2647 | 0.007 | 13.7 | -1.55 | -0.096 | |||||
17 688.64 | 11/2 | 375.4553 | 0.001 | 2.0 | -2.37 | -0.075 | |||||
46 157.19 | 3/2 | 3928.94 | 5/2 | 236.7360 | 0.863 | 616.6 | 0.880 | 628.5 | -0.28 | 0.337 | |
![]() |
5592.05 | 3/2 | 246.4425 | 0.014 | 10.0 | -2.04 | 0.014 | ||||
6636.57 | 1/2 | 252.9564 | 0.031 | 22.4 | 0.029 | 20.7 | -1.70 | -0.021 | |||
7891.93 | 5/2 | 261.2556 | 0.028 | 19.8 | 0.008 | 5.7 | -2.23 | 0.006 | |||
13 136.61 | 3/2 | 302.7533 | 0.008 | 5.7 | -2.11 | -0.016 | |||||
13 414.80 | 5/2 | 305.3257 | 0.001 | 0.7 | -3.01 | 0.001 | |||||
17 424.39 | 3/2 | 347.9347 | 0.018 | 12.8 | -1.63 | 0.093 | |||||
17 569.40 | 5/2 | 349.6996 | 0.026 | 18.6 | -1.47 | -0.072 | |||||
46 373.51 | 5/2 | 3593.15 | 7/2 | 233.6805 | 0.773 | 828.5 | 0.772 | 772.0 | -0.20 | 0.342 | |
![]() |
3928.94 | 5/2 | 235.5293 | 0.113 | 121.5 | 0.080 | 80.0 | -1.18 | 0.052 | ||
5592.05 | 3/2 | 245.1352 | 0.038 | 41.0 | 0.057 | 57.0 | -1.29 | -0.041 | |||
7891.93 | 5/2 | 259.7869 | 0.012 | 12.0 | -1.91 | 0.014 | |||||
11 459.90 | 7/2 | 286.3372 | 0.013 | 13.0 | -1.80 | 0.025 | |||||
11 654.08 | 5/2 | 287.9387 | 0.006 | 6.0 | -2.13 | -0.024 | |||||
13 136.61 | 3/2 | 300.7828 | 0.001 | 1.0 | -2.87 | 0.003 | |||||
13 203.88 | 7/2 | 301.3928 | 0.007 | 7.0 | -2.02 | -0.035 | |||||
13 414.80 | 5/2 | 303.3216 | 0.037 | 37.0 | -1.29 | 0.084 | |||||
17 242.26 | 7/2 | 343.1756 | 0.001 | 1.0 | -2.75 | 0.018 | |||||
17 569.40 | 5/2 | 347.0733 | 0.008 | 8.0 | -1.84 | 0.043 | |||||
48 128.08 | 1/2 | 5592.05 | 3/2 | 235.0229 | 0.708 | 240.2 | 0.768 | 260.3 | -0.67 | 0.320 | |
![]() |
6636.57 | 1/2 | 240.9399 | 0.083 | 28.1 | 0.099 | 33.5 | -1.54 | -0.118 | ||
13 136.61 | 3/2 | 285.7000 | 0.027 | 9.1 | -1.95 | -0.040 | |||||
17 424.39 | 3/2 | 325.5998 | 0.005 | 1.7 | -2.57 | -0.021 | |||||
48 798.70 | 5/2 | 3928.94 | 5/2 | 222.7980 | 0.606 | 542.7 | 0.484 | 433.4 | -0.49 | -0.155 | |
![]() |
5592.05 | 3/2 | 231.3747 | 0.162 | 145.2 | 0.278 | 248.9 | -0.70 | -0.121 | ||
7891.93 | 5/2 | 244.3842 | 0.044 | 39.1 | 0.036 | 32.2 | -1.54 | -0.015 | |||
11 459.90 | 7/2 | 267.7384 | 0.029 | 26.0 | -1.55 | -0.028 | |||||
11 654.08 | 5/2 | 269.1381 | 0.027 | 24.3 | 0.023 | 20.6 | -1.65 | -0.024 | |||
13 136.61 | 3/2 | 280.3272 | 0.001 | 0.9 | -2.97 | 0.001 | |||||
13 414.80 | 5/2 | 282.5313 | 0.025 | 22.4 | -1.57 | 0.017 | |||||
17 242.26 | 7/2 | 316.8008 | 0.001 | 0.9 | -2.87 | 0.005 | |||||
17 424.39 | 3/2 | 318.6400 | 0.056 | 50.1 | -1.12 | -0.119 | |||||
17 569.40 | 5/2 | 320.1196 | 0.008 | 7.2 | -1.96 | 0.014 | |||||
19 985.93 | 7/2 | 346.9690 | 0.003 | 2.7 | -2.31 | -0.013 | |||||
49 149.39 | 7/2 | 0.00 | 9/2 | 203.3959 | 0.014 | 16.7 | -1.98 | 0.005 | |||
![]() |
3593.15 | 7/2 | 219.4403 | 0.696 | 831.0 | -0.22 | -0.259 | ||||
3928.94 | 5/2 | 221.0700 | 0.011 | 13.1 | -2.02 | -0.006 | |||||
7891.93 | 5/2 | 242.3068 | 0.175 | 208.9 | -0.73 | -0.125 | |||||
11 459.90 | 7/2 | 265.2470 | 0.009 | 10.7 | -1.95 | -0.011 | |||||
11 654.08 | 5/2 | 266.6207 | 0.012 | 14.3 | -1.82 | -0.024 | |||||
13 203.88 | 7/2 | 278.1168 | 0.003 | 3.6 | -2.38 | -0.009 | |||||
13 414.80 | 5/2 | 279.7584 | 0.011 | 13.1 | -1.81 | 0.015 | |||||
15 605.58 | 9/2 | 298.0306 | 0.001 | 1.2 | -2.80 | 0.019 | |||||
17 569.40 | 5/2 | 316.5646 | 0.048 | 57.3 | -1.06 | -0.154 | |||||
19 590.91 | 5/2 | 338.2153 | 0.002 | 2.4 | -2.38 | 0.017 | |||||
19 985.93 | 7/2 | 342.7965 | 0.002 | 2.4 | -2.37 | 0.0143 | |||||
51 770.38 | 5/2 | 3593.15 | 7/2 | 207.5008 | 0.001 | 1.0 | -3.19 | 0.000 | |||
[![]() |
3928.94 | 5/2 | 208.9573 | 0.048 | 35.5 | -1.63 | -0.011 | ||||
5592.05 | 3/2 | 216.4838 | 0.562 | 413.6 | -0.54 | -0.204 | |||||
7891.93 | 5/2 | 227.8319 | 0.148 | 109.1 | -1.07 | 0.037 | |||||
11 459.90 | 7/2 | 247.9995 | 0.028 | 20.7 | -1.72 | -0.023 | |||||
11 654.08 | 5/2 | 249.2001 | 0.062 | 45.3 | -1.37 | 0.034 | |||||
13 136.61 | 3/2 | 258.7635 | 0.004 | 3.2 | -2.49 | 0.005 | |||||
13 203.88 | 7/2 | 259.2149 | 0.001 | 1.0 | -3.00 | -0.002 | |||||
13 414.80 | 5/2 | 260.6404 | 0.034 | 24.8 | -1.60 | -0.013 | |||||
17 242.26 | 7/2 | 289.5341 | 0.001 | 0.8 | -3.00 | 0.005 | |||||
17 424.39 | 3/2 | 291.0696 | 0.058 | 42.6 | -1.27 | -0.124 | |||||
17 569.40 | 5/2 | 292.340 | 0.004 | 3.1 | -2.40 | 0.006 | |||||
19 590.91 | 5/2 | 310.6670 | 0.002 | 1.3 | -2.72 | -0.005 | |||||
19 985.93 | 7/2 | 314.5281 | 0.003 | 2.2 | -2.49 | -0.0103 | |||||
51 951.61 | 9/2 | 0.00 | 9/2 | 192.4868 | 0.259 | 810.7 | 0.182 | 568.7 | -0.50 | 0.117 | |
![]() |
3593.15 | 7/2 | 206.7230 | 0.442 | 1381.7 | 0.562 | 1756.2 | 0.05 | -0.501 | ||
11 459.90 | 7/2 | 246.8895 | 0.089 | 277.2 | 0.089 | 278.1 | -0.59 | 0.121 | |||
13 203.88 | 7/2 | 258.0024 | 0.161 | 502.9 | 0.097 | 303.1 | -0.52 | -0.189 | |||
15 605.58 | 9/2 | 275.0519 | 0.011 | 34.3 | -1.41 | -0.058 | |||||
17 242.26 | 7/2 | 288.0223 | 0.012 | 37.5 | -1.33 | 0.047 | |||||
17 688.64 | 11/2 | 291.7749 | 0.009 | 28.2 | -1.44 | 0.166 | |||||
21 590.81 | 9/2 | 329.2772 | 0.002 | 6.2 | -2.00 | 0.023 | |||||
52 206.48 | 7/2 | 0.00 | 9/2 | 191.5471 | 0.001 | 1.6 | -3.05 | -0.001 | |||
![]() |
3593.15 | 7/2 | 205.6391 | 0.440 | 749.6 | - | - | - | 0.000 | ||
3928.94 | 5/2 | 207.0696 | 0.415 | 706.9 | 0.632 | 1031.8 | -0.18 | -0.364 | |||
7891.93 | 5/2 | 225.5896 | 0.002 | 3.3 | -2.60 | 0.001 | |||||
11 459.90 | 7/2 | 245.3451 | 0.060 | 98.0 | -1.05 | -0.051 | |||||
11 654.08 | 5/2 | 246.5200 | 0.022 | 35.9 | -1.48 | 0.044 | |||||
13 203.88 | 7/2 | 256.3163 | 0.112 | 182.8 | -0.74 | 0.137 | |||||
13 414.80 | 5/2 | 257.7101 | 0.037 | 60.4 | -1.22 | -0.044 | |||||
15 605.58 | 9/2 | 273.1365 | 0.047 | 76.7 | -1.07 | 0.112 | |||||
17 569.40 | 5/2 | 288.6233 | 0.028 | 48.3 | 0.018 | 29.4 | -1.43 | -0.055 | |||
19 590.91 | 5/2 | 306.5129 | 0.001 | 1.6 | -2.65 | 0.004 | |||||
21 590.81 | 9/2 | 326.5360 | 0.005 | 8.2 | -1.88 | -0.024 | |||||
54 379.27 | 7/2 | 0.00 | 9/2 | 183.8936 | 0.001 | 2.0 | -2.99 | 0.001 | |||
![]() |
3593.15 | 7/2 | 196.9042 | 0.023 | 46.0 | -1.57 | 0.013 | ||||
3928.94 | 5/2 | 198.2148 | 0.329 | 658.0 | -0.41 | -0.282 | |||||
7891.93 | 5/2 | 215.0447 | 0.095 | 190.0 | -0.88 | -0.103 | |||||
11 459.90 | 7/2 | 232.9235 | 0.076 | 152.0 | -0.91 | 0.057 | |||||
11 654.08 | 5/2 | 233.9822 | 0.011 | 22.0 | -1.74 | 0.031 | |||||
13 203.88 | 7/2 | 242.7898 | 0.230 | 460.0 | -0.39 | -0.228 | |||||
13 414.80 | 5/2 | 244.0400 | 0.019 | 38.0 | -1.47 | -0.041 | |||||
15 605.58 | 9/2 | 257.8296 | 0.061 | 122.0 | -0.91 | -0.113 | |||||
17 242.26 | 7/2 | 269.1932 | 0.015 | 30.0 | -1.49 | -0.025 | |||||
17 569.40 | 5/2 | 271.5858 | 0.009 | 18.0 | -1.70 | -0.020 | |||||
19 590.91 | 5/2 | 287.3681 | 0.002 | 4.0 | -2.30 | 0.007 | |||||
19 985.93 | 7/2 | 290.6688 | 0.001 | 2.0 | -2.60 | 0.002 | |||||
21 590.81 | 9/2 | 304.8967 | 0.023 | 46.0 | -1.19 | 0.072 | |||||
54 445.19 | 5/2 | 3593.15 | 7/2 | 196.6489 | 0.057 | 81.4 | -1.33 | -0.094 | |||
![]() |
3928.94 | 5/2 | 197.9561 | 0.121 | 172.8 | -0.99 | -0.115 | ||||
5592.05 | 3/2 | 204.6295 | 0.002 | 2.9 | -2.74 | 0.004 | |||||
7891.93 | 5/2 | 214.7401 | 0.076 | 108.6 | -1.12 | 0.051 | |||||
11 459.90 | 7/2 | 232.5663 | 0.380 | 542.9 | -0.36 | 0.238 | |||||
11 654.08 | 5/2 | 233.6218 | 0.013 | 18.6 | -1.82 | -0.029 | |||||
13 136.61 | 3/2 | 242.0069 | 0.047 | 67.1 | -1.23 | 0.071 | |||||
13 203.88 | 7/2 | 242.4017 | 0.185 | 264.3 | -0.63 | -0.132 | |||||
13 414.80 | 5/2 | 243.6479 | 0.001 | 1.4 | -2.90 | -0.001 | |||||
17 242.26 | 7/2 | 268.7162 | 0.037 | 52.8 | -1.24 | 0.052 | |||||
17 424.39 | 3/2 | 270.0383 | 0.006 | 8.6 | -2.03 | -0.018 | |||||
17 569.40 | 5/2 | 271.1003 | 0.006 | 8.6 | -2.03 | -0.005 | |||||
19 590.91 | 5/2 | 286.8246 | 0.011 | 15.7 | -1.71 | -0.024 | |||||
19 985.93 | 7/2 | 290.1127 | 0.011 | 15.7 | -1.70 | 0.024 |
a Van Kleef & Klinkenberg (1961) b Wavelengths are given in vacuum below 200.0 nm and in air above that limit. They are deduced from experimental level values. c Ivarsson et al. (2004) d This work. e Values obtained by combining calculated BFs and experimental lifetimes given in the first column and taken from: f This work and g Ivarsson et al. (2004). Values between brackets are calculated values in this work. h Cancellation factor (see text). A very small value (typically <0.01) of CF means that strong cancellation effects are present in the calculation of the corresponding transition rate. |