Upper levela | J | Lower levela | J | ![]() |
Experimentc | This work | ||||
Energy (cm-1) | Energy (cm-1) | BF | gA | BFd | gAe | log gfe | ||||
22 615.69 | 4 | 0.00 | 4 | 442.0468 | 0.983 | 0.963 | 21.69 | -1.20 | ||
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4159.32 | 3 | 541.6678 | 0.001 | 0.002 | 0.09 | -3.40 | |||
5143.92 | 5 | 572.1931 | 0.012 | 0.028 | 0.63 | -2.51 | ||||
11 030.58 | 4 | 862.9399 | 0.006 | 0.18 | -2.70 | |||||
23 462.90 | 5 | 0.00 | 4 | 426.0848 | 0.992 | 13.64 | 0.987 | 13.53 | -1.43 | |
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5143.92 | 5 | 545.7302 | 0.011 | 0.11 | -3.31 | ||||
28 331.77 | 4 | 0.00 | 4 | 352.8598 | 0.287 | 9.72 | 0.362 | 14.13 | -1.58 | |
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4159.32 | 3 | 413.5774 | 0.515 | 17.46 | 0.568 | 22.23 | -1.24 | ||
5143.92 | 5 | 431.1391 | 0.195 | 6.57 | 0.045 | 1.80 | -2.30 | |||
8742.83 | 4 | 510.3499 | 0.002 | 0.09 | 0.022 | 0.81 | -2.50 | |||
28 371.68 | 3 | 0.00 | 4 | 352.3634 | 0.255 | 4.55 | -2.07 | |||
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2740.49 | 2 | 390.0391 | 0.377 | 6.79 | -1.81 | ||||
4159.32 | 3 | 412.8957 | 0.214 | 3.85 | -2.01 | |||||
10 165.98 | 2 | 549.1259 | 0.009 | 0.14 | -3.20 | |||||
11 030.58 | 4 | 576.5048 | 0.020 | 0.35 | -2.76 | |||||
11 378.00 | 3 | 588.2910 | 0.034 | 0.63 | -2.48 | |||||
13 364.83 | 2 | 666.1784 | 0.016 | 0.28 | -2.73 | |||||
14 091.37 | 3 | 700.0718 | 0.005 | 0.07 | -3.29 | |||||
15 222.57 | 2 | 760.2984 | 0.059 | 1.05 | -2.04 | |||||
15 390.76 | 3 | 770.1494 | 0.007 | 0.14 | -2.90 | |||||
29 381.65 | 3 | 0.00 | 4 | 340.2508 | 0.059 | 4.20 | -2.14 | |||
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2740.49 | 2 | 375.2524 | 0.707 | 49.98 | -0.98 | ||||
4159.32 | 3 | 396.3619 | 0.149 | 10.50 | -1.61 | |||||
10 165.98 | 2 | 520.2637 | 0.067 | 4.76 | -1.71 | |||||
13 364.83 | 2 | 624.1710 | 0.001 | 0.07 | -3.39 | |||||
14 091.37 | 3 | 653.8296 | 0.004 | 0.28 | -2.75 | |||||
15 222.57 | 2 | 706.0659 | 0.002 | 0.14 | -2.98 | |||||
15 390.76 | 3 | 714.5538 | 0.008 | 0.56 | -2.37 | |||||
30 279.95 | 5 | 0.00 | 4 | 330.1565 | 0.935 | 110.55 | 0.950 | 112.31 | -0.74 | |
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5143.92 | 5 | 397.7228 | 0.061 | 7.26 | 0.041 | 4.84 | -1.94 | ||
8742.83 | 4 | 464.1846 | 0.003 | 0.33 | 0.002 | 0.22 | -3.15 | |||
11 030.58 | 4 | 0.004 | 0.44 | -2.75 | ||||||
30 591.45 | 4 | 0.00 | 4 | 326.7945 | 0.554 | 50.85 | -1.09 | |||
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4159.32 | 3 | 378.2200 | 0.427 | 39.15 | -1.08 | ||||
8742.83 | 4 | 457.5666 | 0.001 | 0.09 | -3.55 | |||||
11 030.58 | 4 | 511.0823 | 0.007 | 0.63 | -2.61 | |||||
11 378.00 | 3 | 520.3238 | 0.002 | 0.18 | -3.14 | |||||
15 390.76 | 3 | 657.6832 | 0.007 | 0.63 | -2.39 | |||||
32 684.61 | 4 | 0.00 | 4 | 305.8655 | 0.883 | 283.77 | 0.864 | 277.65 | -0.41 | |
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4159.32 | 3 | 350.4658 | 0.044 | 14.13 | 0.061 | 19.62 | -1.44 | ||
5143.92 | 5 | 362.9956 | 0.002 | 0.72 | 0.014 | 4.50 | -2.05 | |||
8742.83 | 4 | 417.5622 | 0.042 | 13.59 | 0.026 | 8.28 | -1.66 | |||
11 030.58 | 4 | 461.6785 | 0.017 | 5.40 | 0.016 | 5.13 | -1.78 | |||
11 378.00 | 3 | 469.2066 | 0.007 | 2.25 | 0.003 | 0.99 | -2.48 | |||
14 091.37 | 3 | 537.6804 | 0.004 | 1.26 | -2.26 | |||||
14 338.99 | 5 | 544.9378 | 0.001 | 0.36 | -2.79 | |||||
15 390.76 | 3 | 578.0799 | 0.007 | 2.25 | -1.95 | |||||
33 124.48 | 3 | 0.00 | 4 | 301.8036 | 0.867 | 119.00 | -0.79 | |||
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2740.49 | 2 | 329.0259 | 0.020 | 2.73 | -2.35 | ||||
4159.32 | 3 | 345.1435 | 0.008 | 1.12 | -2.70 | |||||
8742.83 | 4 | 410.0288 | 0.007 | 0.98 | -2.61 | |||||
11 030.58 | 4 | 452.4867 | 0.024 | 3.29 | -1.99 | |||||
11 378.00 | 3 | 459.7157 | 0.001 | 0.14 | -3.35 | |||||
12 774.38 | 2 | 491.2609 | 0.013 | 1.75 | -2.20 | |||||
13 364.83 | 2 | 505.9408 | 0.001 | 0.14 | -3.27 | |||||
15 222.57 | 2 | 558.4445 | 0.055 | 7.56 | -1.45 | |||||
34 365.33 | 5 | 0.00 | 4 | 290.9057 | 0.978 | 448.47 | 0.988 | 434.72 | -0.26 | |
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8742.83 | 4 | 390.1714 | 0.007 | 3.08 | 0.007 | 3.08 | -2.15 | ||
11030.58 | 4 | 428.449 | 0.010 | 4.40 | 0.003 | 1.32 | -2.44 | |||
34 803.82 | 4 | 0.00 | 4 | 287.2405 | 0.133 | 20.61 | -1.59 | |||
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4159.32 | 3 | 326.2288 | 0.464 | 72.00 | -0.94 | ||||
5143.92 | 5 | 337.0587 | 0.310 | 48.06 | -1.09 | |||||
8742.83 | 4 | 383.6064 | 0.042 | 6.48 | -1.84 | |||||
11 030.58 | 4 | 420.5225 | 0.003 | 0.45 | -2.92 | |||||
11 378.00 | 3 | 426.7593 | 0.002 | 0.27 | -3.13 | |||||
14 091.37 | 3 | 482.6665 | 0.006 | 0.90 | -2.50 | |||||
15 390.76 | 3 | 514.9737 | 0.032 | 4.95 | -1.71 | |||||
18 901.94 | 3 | 628.6826 | 0.004 | 0.63 | -2.43 | |||||
35 615.92 | 3 | 0.00 | 4 | 280.6906 | 0.611 | 137.97 | -0.79 | |||
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2740.49 | 2 | 304.0900 | 0.252 | 56.91 | -1.10 | ||||
4159.32 | 3 | 317.8064 | 0.024 | 5.39 | -2.09 | |||||
8742.83 | 4 | 372.0136 | 0.052 | 11.76 | -1.61 | |||||
11 030.58 | 4 | 406.6316 | 0.006 | 1.33 | -2.48 | |||||
11 378.00 | 3 | 412.4603 | 0.016 | 3.64 | -2.03 | |||||
12 774.38 | 2 | 437.6759 | 0.005 | 1.12 | -2.49 | |||||
13 364.83 | 2 | 449.2901 | 0.006 | 1.33 | -2.39 | |||||
14 848.05 | 4 | 481.3785 | 0.004 | 0.91 | -2.50 | |||||
15 222.57 | 2 | 490.2190 | 0.016 | 3.64 | -1.88 | |||||
15 390.76 | 3 | 494.2957 | 0.003 | 0.70 | -2.59 | |||||
18 901.94 | 3 | 598.1358 | 0.001 | 0.21 | -2.95 | |||||
21 303.36 | 2 | 698.4944 | 0.001 | 0.21 | -2.81 | |||||
36 826.39 | 4 | 0.00 | 4 | 271.4639 | 0.422 | 84.42 | -1.03 | |||
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4159.32 | 3 | 306.0297 | 0.040 | 8.01 | -1.95 | ||||
5143.92 | 5 | 315.5406 | 0.005 | 0.99 | -2.83 | |||||
8742.83 | 4 | 355.9785 | 0.281 | 56.16 | -0.97 | |||||
11 030.58 | 4 | 387.5500 | 0.002 | 0.36 | -3.09 | |||||
11 378.00 | 3 | 392.8409 | 0.027 | 5.40 | -1.90 | |||||
14 091.37 | 3 | 439.7265 | 0.061 | 12.15 | -1.45 | |||||
14 338.99 | 5 | 444.5687 | 0.009 | 1.80 | -2.27 | |||||
14 848.05 | 4 | 454.8659 | 0.040 | 8.01 | -1.60 | |||||
15 390.76 | 3 | 466.3824 | 0.103 | 20.61 | -1.17 | |||||
19 108.87 | 4 | 564.2565 | 0.007 | 1.44 | -2.16 | |||||
21 123.66 | 3 | 636.6559 | 0.002 | 0.36 | -2.66 | |||||
37 908.77 | 4 | 0.00 | 4 | 263.7126 | 0.759 | 243.90 | -0.59 | |||
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4159.32 | 3 | 296.2146 | 0.124 | 39.87 | -1.28 | ||||
5143.92 | 5 | 305.1164 | 0.016 | 5.13 | -2.14 | |||||
8742.83 | 4 | 342.7674 | 0.077 | 24.75 | -1.36 | |||||
11 378.00 | 3 | 376.8138 | 0.004 | 1.26 | -2.57 | |||||
14 091.37 | 3 | 419.7428 | 0.007 | 2.25 | -2.23 | |||||
14 848.05 | 4 | 433.5159 | 0.007 | 2.25 | -2.20 | |||||
18 901.94 | 3 | 525.9803 | 0.002 | 0.63 | -2.58 | |||||
40 361.92 | 4 | 0.00 | 4 | 247.6835 | 0.127 | 134.46 | -0.91 | |||
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4159.32 | 3 | 276.1417 | 0.076 | 80.46 | -1.04 | ||||
5143.92 | 5 | 283.8622 | 0.744 | 787.77 | -0.02 | |||||
8742.83 | 4 | 316.1731 | 0.023 | 24.39 | -1.44 | |||||
11 378.00 | 3 | 344.9201 | 0.009 | 9.54 | -1.77 | |||||
14 848.05 | 4 | 391.8327 | 0.017 | 18.00 | -1.38 | |||||
46 776.29 | 3 | 0.00 | 4 | 213.7161 | 0.272 | 396.69 | -0.57 | |||
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2740.49 | 2 | 227.0178 | 0.294 | 428.75 | -0.48 | ||||
4159.32 | 3 | 234.5765 | 0.023 | 33.53 | -1.56 | |||||
8742.83 | 4 | 262.8480 | 0.025 | 36.47 | -1.42 | |||||
10 165.98 | 2 | 273.0663 | 0.021 | 30.59 | -1.47 | |||||
11 030.58 | 4 | 279.6714 | 0.090 | 131.25 | -0.81 | |||||
11 378.00 | 3 | 282.4164 | 0.034 | 49.56 | -1.23 | |||||
12 774.38 | 2 | 294.0151 | 0.001 | 1.47 | -2.72 | |||||
13 364.83 | 2 | 299.2112 | 0.008 | 11.69 | -1.80 | |||||
14 091.37 | 3 | 305.8626 | 0.013 | 18.97 | -1.57 | |||||
14 848.05 | 4 | 313.1116 | 0.116 | 169.19 | -0.60 | |||||
15 222.57 | 2 | 316.8282 | 0.073 | 106.47 | -0.79 | |||||
19 108.87 | 4 | 361.3329 | 0.002 | 2.94 | -2.24 | |||||
19 410.66 | 2 | 365.3178 | 0.003 | 4.34 | -2.06 | |||||
21 123.66 | 3 | 389.7132 | 0.002 | 2.94 | -2.17 | |||||
21 303.36 | 2 | 392.4625 | 0.001 | 1.47 | -2.47 | |||||
23 317.60 | 2 | 426.1613 | 0.003 | 4.34 | -1.93 | |||||
23 984.58 | 3 | 438.6328 | 0.001 | 1.47 | -2.37 | |||||
25 601.55 | 4 | 472.1287 | 0.003 | 4.34 | -1.84 | |||||
27 350.96 | 3 | 514.6484 | 0.002 | 2.94 | -1.93 | |||||
28 139.52 | 3 | 536.4245 | 0.002 | 2.94 | -1.90 | |||||
29 394.30 | 4 | 575.1486 | 0.003 | 4.34 | -1.67 |
a From Van Kleef & Klinkenberg (1961). b Wavelengths in air are deduced from experimental level values. c From Ivarsson et al. (2003) d Branching fractions calculated using the HFR + CP method (see text). e Values obtained by combining calculated BFs and experimental lifetimes given in the first column and taken from: f This work. g Kwiatkowski et al. (1984). h Ivarsson et al. (2003). |