\begin{table}%t4
%\centering
\par
\caption{Location and designation of the resonances in the photoionization spectrum of F$^{4+}$. See caption to Table \ref{tab2}. The peak numbers refer to Fig.~\ref{fig3}. The accuracy of the experimental energies listed is about 200~meV.\label{tab4}}
\begin{tabular}{lllllll}
\hline\hline
Peak & \multicolumn{3}{c}{Energy (eV)}& Transition \\
& Exp. & MCDF & NIST & \\
\hline
1* & 106.05 & 105.4 & 105.97 & 2s2p($^{3}$P)6d $^{4}$D, $^{4}$P \\
2* & 108.60 & 108.0 && 2s2p($^{3}$P)7d $^{4}$D, $^{4}$P \\
3* & 110.32 & 109.6 && 2s2p($^{3}$P)8d $^{4}$D, $^{4}$P \\
4* & 111.43 & 110.8 && 2s2p($^{3}$P)9d $^{4}$D, $^{4}$P \\
5 & 116.31 & 115.4 && 2s2p($^{3}$P)6p $^{2}$P, $^{2}$D, $^{2}$S \\
6 & 118.97 & 117.9 && 2s2p($^{3}$P)7p $^{2}$P, $^{2}$D \\
7 & 120.83 & 118.7 && 2s2p($^{3}$P)8p $^{2}$P, $^{2}$D \\
8 & 122.7 & 123.3 $\left\{ \begin{array}{l} \\ \end{array}\right. $&& $\!\!\begin{array}{l} {\rm 2s2p}(^{1}{\rm P)5p} ^{2}{\rm P},^{2}{\rm D} \\ {\rm 2s2p}(^{3}{\rm P})(n \ge 9){\rm p} \end{array} $ \\
9 & 127.1 & 127.9 && 2s2p($^{1}$P)6p $^{2}$P, $^{2}$D \\
	\hline
	\end{tabular}
\end{table}