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Figure 1: Four six-membered cyclic aromatic molecules: 1. benzene; 2. pyridine; 3. pyrimidine; and 4. 1,3,5-triazine (or s-triazine), having zero, one, two, and three nitrogens per ring, respectively. |
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Figure 2:
The FT-IR spectra of pyridine, pyrimidine and s-triazine
( top to bottom) isolated in an argon matrix at 12 K in the ranges 3500-3000 cm-1
( left panels) and 1800-600 cm-1 ( right panels) with a resolution of 1 cm-1. The matrix isolated molecules were irradiated with UV for 10 s, 1 and 10 min. The vertical scale bars indicate the infra-red absorption in absorption units. Band assignments are presented in Table 1. New bands appearing after photolysis are designated by asterisks (![]() |
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Figure 3: The half-lives of the three N-heterocycles plotted against the number of nitrogen atoms in the ring. Also included in this graph is the half-life of benzene, taken from Ruiterkamp et al. (2005). This plot shows that the photostability of small heterocyclic molecules decreases when an increasing number of nitrogen atoms is incorporated in the ring. The error bars indicate the standard deviation of the linear fit used in the calculation of the half-lives of those molecules. |
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Figure 4:
The relative column densities of s-triazine and its photoproducts during photolysis. Shown in the graph are s-triazine (graph: ![]() ![]() ![]() |
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