\begin{table}%[htb]%t6
\par
%\centering
\par
\caption{Stabilisation energy and important geometric properties
for the CO$_2$:CH$_3$OH complexes.
Intensities (km~mol$^{-1}$) are in parentheses.\label{complex_energies}}
\begin{tabular}{c c c c c c c}\hline\hline
 & 	Distance	& Angle	& Energy	& In plane mode	& OOP mode	& Split \\
 & 	(\AA)	& (deg)	& (kcal~mol$^{-1}$) &	(cm$^{-1}$)	& (cm$^{-1}$)	& (cm$^{-1}$) \\
\hline 
Vertical staggered  \\
B3LYP/6-311++G**	& 2.7548	& 177.33	& 2.66	& 651.36 (64.0)	& 672.77 (33.1)	& 21.41 \\
B3LYP/6-311++G*	& 2.7074	& 177.01	& 3.05	& 649.16 (67.1)	& 673.41 (34.1)	& 24.25 \\
MP2/6-311++G*	& 2.6712	& 177.26	& 4.58	& 639.65 (49.2)	& 661.40 (25.5)	& 21.75 \\
\hline 
Horizontal staggered \\
B3LYP/6-311++G*	& 2.9154	& 177.81	& 1.70	& 654.32 (56.1)	& 673.47 (29.8)	& 19.15 \\
MP2/6-311++G*	& 2.8237	& 177.86	& 3.03	& 638.79 (42.9)	& 661.05 (22.2)	& 22.26 \\
\hline 
Vertical eclipsed \\
B3LYP/6-311++G*	& 2.7180	& 177.05	& 2.99	& 649.03 (66.9)	& 673.39 (33.58)	& 24.36 \\
MP2/6-311++G*	& 2.6794	& 177.28	& 4.42	& 638.91 (49.3)	& 661.78 (25.4)	& 22.87 \\
\hline 
Horizontal eclipsed \\
B3LYP/6-311++G*	& 2.9010	& 177.73	& 1.81	& 653.77 (56.6)	& 673.46 (29.9)	& 19.69 \\
MP2/6-311++G*	& 2.8124	& 177.84	& 3.14	& 638.69 (42.5)	& 660.74 (22.6)	& 22.05 \\
\hline
\end{tabular}
\end{table}