\begin{table}%T1
\caption{\rm {Parameters for the optimized orbitals.}\label{tab1}}
%\centering
\par
\begin{tabular}{c| c c c|c c c}
\hline\hline
& &K VIII & & & Ti XI &  \\
Orbitals&$p_j$&$\xi_j$ &$C_j$&$p_j$&$\xi_j$ &$C_j$ \\
\hline
3p&2&5.8986206 & 0.4001453 &2& 13.0854075 & 0.1046845 \\
  &2& 11.2074413 & 0.0971636 &2& 6.9294436 & 0.4760082 \\
  &3& 3.3184265 & $-$1.1389354 &3& 4.3222458 & $-$1.1986132 \\
3d&3& 6.7592894 & 0.0801860&3& 8.5673148 & 0.0770588 \\
  &3& 2.9913336 & 0.9522927&3& 4.0341888 & 0.9507110 \\
4s&1& 15.2000205 & 0.0939256 &1& 15.2983070 & 0.1290024 \\
  &2& 7.0118243 & $-$0.1769061&2& 11.2757064 & $-$0.0989372 \\
  &2& 1.8368330 & $-$3.3274061&2& 2.5035395 & $-$4.4350670 \\
  &3& 3.2678086 & 3.1927168 &3& 4.1167294 & 4.2864968 \\
4p&2& 7.7052228 & 0.1714105&2& 8.8231176 & 0.2983943 \\
  &2& 1.5705746 & 2.3866439 &2& 1.4850941 & $-$0.0757807 \\
  &3& 3.1453231 & $-$2.1808499 &3& 3.0626329 & $-$76.9581643 \\
  & & & &3&3.0319666& 77.3170529 \\
4d&3& 1.6722706 & 1.4733928&3& 2.3154917 & 1.5549609 \\
   &3& 3.0419079 & $-$1.0736863&3& 4.0354790 & $-$1.1643178 \\
4f&4& 2.0370563 & 1.000&4& 2.90000 & 1.000 \\
\hline
\end{tabular}
\end{table}