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A&A 437, 501-515 (2005)
DOI: 10.1051/0004-6361:20042060
H
CO and CH
OH abundances in the envelopes around low-mass protostars
J. K. Jørgensen1, F. L. Schöier2 and E. F. van Dishoeck1 1 Leiden Observatory, PO Box 9513, 2300 RA Leiden, The Netherlands
e-mail: jjorgensen@cfa.harvard.edu
2 Stockholm Observatory, AlbaNova, 106 91 Stockholm, Sweden
(Received 23 September 2004 / Accepted 22 March 2005)
Abstract
This paper presents the third in a series of single-dish
studies of molecular abundances in the envelopes around a large
sample of 18 low-mass pre- and protostellar objects. It focuses on
typical grain mantle products and organic molecules, including
H2CO, CH3OH and CH3CN. With a few exceptions, all H2CO
lines can be fit by constant abundances of
throughout the envelopes if ortho- and
para lines are considered independently. The current observational
dataset does not require a large H2CO abundance enhancement in
the inner warm regions, but this can also not be ruled out. Through
comparison of the H2CO abundances of the entire sample, the
H2CO ortho-para ratio is constrained to be
consistent
with thermalization on grains at temperatures of 10-15 K. The
H2CO abundances can be related to the empirical chemical network
established on the basis of our previously reported survey of other
species and is found to be closely correlated with that of the
nitrogen-bearing molecules. These correlations reflect the
freeze-out of molecules at low temperatures and high densities, with
the constant H2CO abundance being a measure of the size of the
freeze-out zone. An improved fit to the data is obtained with a
"drop" abundance structure in which the abundance is typically a
few
10-10 when the temperature is lower than the
evaporation temperature and the density high enough so that the
timescale for depletion is less than the lifetime of the core. The
location of the freeze-out zone is constrained from CO observations. Outside the freeze-out zone, the H2CO abundance is
typically a few
. The observations show that
the CH3OH lines are significantly broader than the H2CO lines,
indicating that they probe kinematically distinct regions. CH3OH
is moreover only detected toward a handful of sources and CH3CN
toward only one, NGC 1333-IRAS2. For NGC 1333-IRAS2, CH3OH and
CH3CN abundance enhancements of two-three orders of magnitude at
temperatures higher than 90 K are derived. In contrast, the
NGC 1333-IRAS4A and IRAS4B CH3OH data are fitted with a constant
abundance and an abundance enhancement at a lower temperature of 30 K, respectively. This is consistent with a scenario where
CH3OH probes the action of compact outflows on the envelopes,
which is further supported by comparison to high frequency, high
excitation CS J=10-9 and HDO line profiles which uniquely probe
warm, dense gas. The extent to which the outflow dominates the
abundance enhancements compared with the passively heated inner
envelope depends on the filling factors of the two components in the
observing beam.
Key words: stars: formation -- ISM: molecules -- ISM: abundances -- radiative transfer -- astrochemistry
SIMBAD Objects
© ESO 2005
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