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Issue A&A
Volume 398, Number 2, February I 2003
Page(s) L11 - L13
Section Letters
DOI http://dx.doi.org/10.1051/0004-6361:20021849



A&A 398, L11-L13 (2003)
DOI: 10.1051/0004-6361:20021849

Letter

The millimeter-wave spectrum and the dipole moment of vinylacetylene

S. Thorwirth and H. Lichau

I. Physikalisches Institut, Universität zu Köln, Zülpicher Str. 77, 50937 Köln, Germany
(Received 20 November 2002 / Accepted 15 December 2002 )

Abstract
The pure rotational spectrum of the hydrocarbon vinylacetylene (1-butene-3-yne, ${\rm H_2C=CH-C\equiv CH}$) in its ground vibrational state has been investigated from 80 to 165 GHz, covering the rotational quantum numbers $ 8 \le J \le 18 $ and $ 0 \le K_{a} \le 17 $, in order to provide accurate rest frequencies for radioastronomical searches. Moreover, quantum chemical calculations of the dipole moment components  $\mu_{a}$ and  $\mu_{b}$ have been performed leading to the result $\mu_{a}\approx0.4$ D. The value for the dipole moment component  $\mu_{b}$ is very low and lies in the range of several thousandth to a few hundredth of a Debeye.


Key words: molecular data -- methods: laboratory -- techniques: spectroscopic -- stars: AGB and post-AGB

Offprint request: S. Thorwirth, sven@ph1.uni-koeln.de


Tables at the CDS



© ESO 2003


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